1469804-79-2Relevant academic research and scientific papers
Regio- and stereochemical controlled koenigs-knorr-type monoglycosylation of secondary hydroxy groups in carbohydrates utilizing the high site recognition ability of organotin catalysts
Muramatsu, Wataru,Yoshimatsu, Hirofumi
, p. 2518 - 2524 (2013)
The catalytic regio- and stereoselective monoglycosylation of carbohydrates using organotin catalysts is demonstrated. The one-step reaction affords various oligosaccharides linked at the secondary hydroxy group in high chemical yield and good regio- and stereoselectivities. The regioselectivity of the glycosylation is shown to depend on the spatial arrangement of the hydroxy groups in the carbohydrates. Copyright
