1470074-09-9Relevant articles and documents
Gentiobiosylation of β-resorcylic acid esters and lactones: First synthesis and characterization of zearalenone-14-β,d-gentiobioside
Weber, Julia,Mikula, Hannes,Fruhmann, Philipp,Hametner, Christian,Varga, Elisabeth,Berthiller, Franz,Krska, Rudolf,Fr?hlich, Johannes
, p. 1830 - 1834 (2013/09/12)
The development of an optimized protocol for the gentiobiosylation of β-resorcylic acid esters and lactones (β-RAL) is presented. Different gentiobiosyl donors were prepared and used for regioselective and diastereoselective glycosylation affording a reliable synthetic strategy towards this class of natural product glycosides. The improved procedure was finally used for the preparation of the masked Fusarium mycotoxin zearalenone-14-β, d-gentiobioside. Georg Thieme Verlag Stuttgart · New York.