1471806-91-3Relevant academic research and scientific papers
Copper-catalysed oxidative Csp3-H methylenation to terminal olefins using DMF
Liu, Jianming,Yi, Hong,Zhang, Xin,Liu, Chao,Liu, Ren,Zhang, Guoting,Lei, Aiwen
supporting information, p. 7636 - 7638 (2014/07/08)
A copper-catalysed direct oxidative Csp3-H methylenation to terminal olefins using DMF as one carbon source was developed. In this reaction, various functional groups were well tolerated, thus providing a simple way to construct arylvinylketones and arylvinylpyridines. The preliminary mechanistic investigations revealed that CH2 was from DMF (N-CH3).
