1472-09-9

Basic information

• Product Name: Octylcyclopropane
• Synonyms: Octylcyclopropane
• CAS NO: 1472-09-9
• Molecular Formula: C₁₁H₂₂
• Molecular Weight: 154.29
• Mol File: 1472-09-9.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 72-75 °C(Press: 12 Torr)
• Appearance: /
• Density: 0.812±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Octylcyclopropane(CAS DataBase Reference)
• NIST Chemistry Reference: Octylcyclopropane(1472-09-9)
• EPA Substance Registry System: Octylcyclopropane(1472-09-9)

Safety Data

• Hazardous Substances Data: 1472-09-9(Hazardous Substances Data)

Upstream product

• 872-05-9 1-Decene 
• 83022-84-8 (1-Octyl-cyclopropylsulfanyl)-benzene 
• 111-83-1 1-bromo-octane 
• 1472-85-1 diethyl octylmalonate 
• 74971-70-3 2-n-octylpropane-1,3-diol 
• 14094-12-3 tert-butyl methyl sulfone 
• 160002-82-4 3-(n-octyl)cyclobutanone 
• 64923-67-7 Methanesulfonic acid 2-methanesulfonyloxymethyl-decyl ester 
• 15997-12-3 1,1-dichloro-2-octyl cyclopropane 
• 2216-87-7 undecan-3-one 
• 186581-53-3 diazomethane 
• 75-11-6 diiodomethane 

Downstream Products

• 1120-21-4 n-Undecane 
• 6975-98-0 2-methyldecane 

Relevant articles and documents

Cyclopropanation of Terminal Olefins Using Diazomethane/Palladium(II) Acetate

-

Mechanism-based design and optimization of a catalytic electrophilic cyclopropanation without diazomethane

Iodomethylboron compounds, either the trifluoroborate or a boronic ester, cyclopropanate electron-rich olefins and unprotected allylic alcohols with Pd catalysts according to a novel, designed catalytic cycle. Proposed intermediates in a "diverted Heck" mechanism are observed by means of spectroscopic studies and by isolation and X-ray crystallographic characterization, which together with reaction kinetics point to a separation of rate-determining and product-determining steps, and a mechanism-based optimization of the yield, selectivity, and scope of the catalytic electrophilic cyclopropanation. The reaction with crystalline, air-stable, nonhygroscopic, and nontoxic reagents provides an alternative to Simmons-Smith-type reactions, as well as cyclopropanation procedures that require the use of diazomethane.

Breaking of the C-C bond of cyclobutanones by rhodium(I) and its extension to catalytic synthetic reactions

A study of rhodium(I)-catalyzed synthetic transformations involving selective breaking of the C-C bond α to the carbonyl group of cyclobutanones is described. Decarbonylation took place on treatment of a cyclobutanone with an equimolar amount of (Ph3