147251-06-7Relevant academic research and scientific papers
Acid-catalysed Thermal Rearrangement of γ,δ-Unsaturated Ketones
Srikrishna, Adusumilli,Krishnan, Kathiresan,Vankateswarlu, Somepalli
, p. 143 - 145 (1993)
Thermal activation of γ,δ-unsaturated ketones (1, 9 and 12) in the presence of a catalytic amount of propionic acid causes a rearrangement to give new γ,δ-unsaturated ketones (2, 10 and 14) via an intramolecular ene reaction followed by a retro-ene reacti
Isomerization of 4-aryl-4-methylhex-5-en-2-ones to 5-aryl-4-methylhex-5-en-2-ones by an intramolecular ene-retro ene reaction sequence
Srikrishna, A.,Krishnan, K.,Venkateswarlu, S.,Kumar, P. Praveen
, p. 2033 - 2038 (2007/10/02)
Acid-catalyzed thermal rearrangement of 4-aryl-4-methylhex-5-en-2-ones (products of the Claisen rearrangement of β-methylcinnamyl alcohols and 2-methoxypropene) to isomeric 5-aryl-4-methylhex-5-en-2-ones via an intramolecular ene reaction of the enol taut
