Acid-catalysed Thermal Rearrangement of γ,δ-Unsaturated Ketones

DOI: 10.1039/c39930000143

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 143 - 145 (1993)

Update date:2022-08-02

Topics:

Authors:

Srikrishna, Adusumilli

Krishnan, Kathiresan

Vankateswarlu, Somepalli

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39930000143

Thermal activation of γ,δ-unsaturated ketones (1, 9 and 12) in the presence of a catalytic amount of propionic acid causes a rearrangement to give new γ,δ-unsaturated ketones (2, 10 and 14) via an intramolecular ene reaction followed by a retro-ene reacti

Full text of DOI:10.1039/c39930000143

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:4,4-dimethyl-5-(p-tolyl)hex-5-en-2-one

Cas No:147251-06-7

R&D Labs maybe for 147251-06-7

Nantong Auxin Electronic Technology Co., LTD

Contact:86-513-88760026

Address:NO.5-1, Aoxin Road, Haian Hi-tech Development Zone, Jiangsu Province, China
Changsha Yihai Chemical Technology Co.,ltd

website:http://www.cs-yihai.com/

Contact:0731- 85620465

Address:Room 23005, unit 2, the northern building of Xiangsong international building , NO.259 Shaoshan Road , Changsha , Hunan, China.(mainland)
Hubei Danao Pharmaceutical Co.,Ltd.

website:http://www.danaopharm.com

Contact:+86-719-5251167

Address:Fandan Road,Danjiangkou,Hubei
TIANJIN ZHONGXIN CHEMTECH CO.,LTD.

Contact:86-022-66880623

Address:FINANCIAL STREET WEST BLK 7, #308, NO.52 XINCHENG WEST ROAD, TEDA, TIANJIN, P.R.CHINA
Zhejiang Kaili Industrial Co., Ltd

Contact:+86-571-85241926

Address:lantian business center,No.18 Moganshan Road

Relevant to this article

Doi:10.1039/jr9480000601
(1948)
Synthesis, characterization and biological activity of new cyclization products of 3-(4-substituted benzylidene)-2H-pyrido[1,2-a]pyrimidine 2,4-(3H)-diones

Doi:10.1007/s12039-013-0367-0
(2013)
Solution- and solid-state structures of N-desmethylnefopam hydrochloride, a metabolite of the analgesic drug

Doi:10.1002/jps.2600820312
(1993)
Mechanism of photo-oxidation of heptafluorobutyric anhydride in the presence of NO₂. Synthesis and characterization of heptafluoropropyl peroxynitrate, CF₃CF₂CF₂OONO₂

Doi:10.1021/jp307172g
(2012)
Enantioselektive Synthese von Allyl-, Propargyl- und 4-En-2-inyl-aminen durch 1,2-Addition von Organocer-Reagenzien an chirale Aldimine

Doi:10.1002/hlca.19950780419
(1995)
Effect of different strains of yeast on stereocontrolled reduction of 5-acetylisoxazolines

Doi:10.1016/S0045-2068(02)00500-X
(2002)

Article Doi