147254-71-5Relevant academic research and scientific papers
Formation of 1,2,4-Trioxepines via 9,10-Dicyanoanthracene(DCA)-sensitized Photo-oxidation of Arylvinyloxiranes
Futamura, Shigeru,Kamiya, Yoshio
, p. 1053 - 1055 (1988)
9,10-Dicyanoanthracene-sensitized photo-oxidation of arylvinyloxiranes in acetonitrile affords the corresponding 1,2,4-trioxepines.
Deoxygenation of 1,3-Diene 1,4-Endoperoxides by Tin(II) Chloride
Kohmoto, Shigeo,Kasai, Satoru,Yamamoto, Makoto,Yamada, Kazutoshi
, p. 1477 - 1478 (1988)
The reaction of bicyclic 1,3-diene 1,4-endoperoxides with SnCl2 re-generated the corresponding dienes in 15-70percent yield.The efficiency of the deoxygenation depended on the structure of peroxides.The results were compared with those of Fe(II) as well as Pd(0) assisted reactions.
Prostaglandin-Synthesen durch Dreikomponenten-Kupplung
Noyori, Ryoji,Suzuki, Masaaki
, p. 854 - 882 (2007/10/02)
Prostaglandine spielen im menschlichen Koerper eine erstaunliche Rolle.Nach der vollstaendigen Strukturaufklaerung Anfang der sechziger Jahre wurden enorme Anstrengungen unternommen, eine leistungsfaehige chemische Synthese zu entwickeln, denn diese in de
STEREOCHEMISTRY OF BIS-(DICHLOROCYCLOPROPANATION) AND -(EPOXIDATION) OF 1,4-DIARYLBUTADIENES
Hashem, Md. Abul,Weyerstahl, Peter,Green, Bernard S.
, p. 203 - 210 (2007/10/02)
Dichlorocyclopropanation as well as epoxidation of the 1,4-diarylbutadienes 1-4 to give the mon- and/or bis-adducts according to several methods were studied.Dichlorocyclopropanation is more affected than epoxidation by sterical hindrance of large substituents as 2,6-dichlorophenyl.The bis-adducts are formed preferably as meso- (or threo-) isomers.
