147381-67-7

Upstream product

• 110-72-5 N-ethylethane-1,2-diamine 
• 103-72-0 phenyl isothiocyanate 

Downstream Products

• 157595-43-2 Cu⁽¹⁺⁾*C₆H₅NHCSN(C₂H₅)CH₂CH₂NHCSNHC₆H₅*Cl^(1-)=CuCl(C₆H₅NHCSN(C₂H₅)C₂H₄NHCSNHC₆H₅) 
• 148052-62-4 {CuCl₂{(C₇H₄NS)N(CH₂)2N(C₂H₅)CNC₆H₅}} 

Relevant academic research and scientific papers

Reactivity of double thioureas towards metal complexes. Synthesis and crystal structure of 2>

By reaction of PhNCS with (MeO)3Si(CH2)3NH(CH2)2NH2 (2:1 molar ratio), a substituted dithiourea has been obtained which affords a new functionalized xerogel (XGditu) by hydrolysis and polycondensation with (EtO)4Si.This material is able to bind metal species, giving systems of potential interest in catalysis.In order to ascertain the nature of the tethered metal species, the non-solixanized dithiourea PhNHC(S)N(Et)(CH2)2NHC(S)NHPh (2) has been prepared.It reacts with to give the complex 2 (4), which contains two distinct hydrido carbonyl clusters bound to the two deprotonated thiourea groups.

NEW DITHIOUREA LIGANDS AS MODELS OF THIOUREA-FUNCTIONALIZED SILICA XEROGELS. CRYSTAL STRUCTURES OF PhNHC(S)N(Et)(CH2)2NHC(S)NHPh AND OF THE DERIVED COMPLEX , CONTAINING A NOVEL N,N-CHELATING LIGAND

By reaction of PhNCS with (EtO)3Si(CH2)3NH(CH2)2NH2 (2:1 molar ratio), a substituted dithiourea ligand has been obtained, affording a new funtionalized xerogel by hydrolysis and polycondensation with (EtO)4Si.This material is able to bind palladium and co