147383-20-8Relevant academic research and scientific papers
An efficient preparation of β-dimethylaminovinyl sulfone and sulfoximide, and investigation of their reactivity as dipolarophiles
Pesa, Nela,Welch, Chris J.,Boa, Andrew N.
, p. 599 - 607 (2007/10/03)
A simple reaction affording (E)-1-dimethylamino-2-phenylsulfonylethylene, and S-((E)-2-(N′N′-dimethylamino)ethenyl)-5-phenyl-N-(p- tolylsulfonyl) sulfoximide in high yields is described. A reversal in regioselectivity was observed when the ss-dimethylamin
Synthesis and Highly Diastereoselective Nucleophilic Epoxidation of N-(p-Tolylsulfonyl)vinylsulfoximines
Bailey, Peter L.,Clegg, William,Jackson, Richard F. W.,Meth-Cohn, Otto
, p. 343 - 350 (2007/10/02)
N-(p-Tolylsulfonyl)vinylsulfoximines 3 may be prepared in good yield in a one-pot process by reaction of lithiated S-methyl-S-phenyl-N-(p-tolylsulfonyl)sulfoximine with aldehydes, followed by elimination using methanesulfonyl chloride-triethylamine.The vi
Very High Diastereofacial Selectivity in the Nucleophilic Epoxidation of N-(p-Tolylsulphonyl)vinylsulphoximines
Bailey, Peter L.,Clegg, William,Jackson, Richard F. W.,Meth-Cohn, Otto
, p. 200 - 202 (2007/10/02)
Nucleophilic epoxidation of N-(p-tolylsulphonyl)vinylsulphoximines (6) using lithium t-butylhydroperoxide proceeds with very high diastereofacial selectivity, the sense of which was established by a single crystal X-ray structure determination, to give N-
