147384-55-2Relevant articles and documents
The first total synthesis of calbistrin A, a microbial product possessing multiple bioactivities
Tatsuta, Kuniaki,Itoh, Manabu,Hirama, Ryusuke,Araki, Nobuyuki,Kitagawa, Masayuki
, p. 583 - 586 (2007/10/03)
The octahydronaphthopyranone moiety is synthesized from methyl α-D-mannopyranoside through the intramolecular Diels-Alder reaction, and the tetraenedicarboxylic acid moiety is from the enzymatically prepared anti-compound. Both moieties were coupled to accomplish the total synthesis of calbistrin A and to disclose its absolute structure.