14743-22-7

Upstream product

• 6738-06-3 phenylethynylmagnesium bromide 
• 108-77-0 1,3,5-trichloro-2,4,6-triazine 
• 536-74-3 phenylacetylene 

Downstream Products

• 1258299-89-6 C₁₅H₁₁ClN₆ 

Relevant academic research and scientific papers

Supramolecular photocatalyst of Palladium (II) Encapsulated within Dendrimer on TiO2 nanoparticles for Photo-induced Suzuki-Miyaura and Sonogashira Cross-Coupling reactions

In this study, synthesis, characterization and catalytic performance of a novel supramolecular photocatalytic system including palladium (II) encapsulated within amine-terminated poly (triazine-triamine) dendrimer modified TiO2 nanoparticles (Pd (II) [PTATAD] @ TiO2) is presented. The obtained nanodendritic catalyst was characterized by FT-IR, ICP-AES, XPS, EDS, TEM, TGA and UV-DRS. The as-prepared nanodendritic catalyst was shown to be highly active, selective, and recyclable for the Suzuki–Miyaura and Sonogashira cross-coupling of a wide range of aryl halides including electron-rich and electron-poor and even aryl chlorides, affording the corresponding biaryl compounds in good to excellent yields under visible light irradiation. This study shows that visible light irradiation can drive the cross-coupling reactions on the Pd (II) [PTATAD] @ TiO2 under mild reaction conditions (27–30?°C) and no additional additives such as cocatalysts or phosphine ligands. So, we propose that the improved photoactivity predominantly benefits from the synergistic effects of Pd (II) amine-terminated poly (triazine-triamine) dendrimer on TiO2 nanoparticles that cause efficient separation and photogenerated electron–hole pairs and photoredox capability of nanocatalyst which all of these advantages due to the tuning of band gap of catalyst in the visible light region.

STYRYL-TRIAZINE DERIVATIVES AND THEIR THERAPEUTICAL APPLICATIONS

The invention provides Styryl-Triazine derivatives, and further provides methods of using these compounds to modulate protein kinases and to treat protein kinase mediated diseases

2-Alkyl-4,6-dialkylamino-1,3,5-triazines via Grignard alkylation of cyanuric chloride: An aged reaction revisited

Suitable one-pot reaction conditions are suggested to prepare, in good overall yields, some 2-(alk-1'-ynyl)- and 2-alkyl-4,6-dialkylamino-1,3,5-triazines via reaction of cyanuric chloride with Grignard reagents followed by amination. (C) 2000 Elsevier Science Ltd.