147444-03-9 Usage
Uses
Pyripyropene A exhibits insecticidal properties and a useful compound for developing agrichemicals.
Definition
ChEBI: A sesquiterpenoid that consists of (3S,4R,4aR,6S,6aS,12R,12aS,12bS)-4-(acetoxymethyl)-12-hydroxy-4,6a,12b-trimethyl-11-o
o-9-(pyridin-3-yl)-1,3,4,4a,5,6,6a,12,12a,12b-decahydro-2H,11H-benzo[f]pyrano[4,3-b]chromene-3,6-diol in which the hydrogens of the 3- and 6-hydroxy functions are substituted by acetyl groups.
Check Digit Verification of cas no
The CAS Registry Mumber 147444-03-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,4,7,4,4 and 4 respectively; the second part has 2 digits, 0 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 147444-03:
(8*1)+(7*4)+(6*7)+(5*4)+(4*4)+(3*4)+(2*0)+(1*3)=129
129 % 10 = 9
So 147444-03-9 is a valid CAS Registry Number.
InChI:InChI=1/C31H37NO10/c1-16(33)38-15-30(5)22-13-24(40-18(3)35)31(6)27(29(22,4)10-9-23(30)39-17(2)34)26(36)25-21(42-31)12-20(41-28(25)37)19-8-7-11-32-14-19/h7-8,11-12,14,22-24,26-27,36H,9-10,13,15H2,1-6H3/t22-,23+,24+,26+,27-,29+,30+,31-/m1/s1
147444-03-9Relevant articles and documents
Total synthesis of pyripyropene A
Odani, Atsuki,Ishihara, Kaoru,Ohtawa, Masaki,Tomoda, Hiroshi,Omura, Satoshi,Nagamitsu, Tohru
, p. 8195 - 8203 (2011/10/31)
The total synthesis of pyripyropene A, a potent ACAT2 inhibitor with high isozyme selectivity, was completed. Key features of the synthetic strategy include Ti(III)-mediated radical cyclization and Peterson olefination for the construction of the AB ring
Relative and absolute stereochemistry of pyripyropene A, A potent, bioavailable inhibitor of Acyl-CoA: Cholesterol acyltransferase (ACAT)
Tomoda, Hiroshi,Nishida, Hiroyuki,Kim, Young Kook,Obata, Rika,Sunazuka, Toshiaki,Omura, Satoshi,Bordner, Jon,Guadliana, Mark,Dormer, Peter G.,Smith III, Amos B.
, p. 12097 - 12098 (2007/10/02)
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