147496-14-8 Usage
Uses
Used in Coordination Chemistry:
6,6'-DIBROMO-[3,3']-BIPYRIDINE is used as a ligand in coordination chemistry for the formation of metal complexes. These complexes are valuable due to their catalytic properties in various chemical reactions, enhancing the efficiency and selectivity of these processes.
Used in Organic Synthesis:
In the field of organic synthesis, 6,6'-DIBROMO-[3,3']-BIPYRIDINE is utilized as a versatile building block. Its reactivity and structural features allow for the creation of a wide range of organic molecules with diverse applications, contributing to the advancement of chemical research and development.
Used in Catalyst Development:
6,6'-DIBROMO-[3,3']-BIPYRIDINE is employed as a key component in the development of catalysts. The metal complexes formed by 6,6'-DIBROMO-[3,3']-BIPYRIDINE are often used to accelerate chemical reactions, making them more efficient and environmentally friendly.
Used in Pharmaceutical Development:
Due to its ability to form stable metal complexes, 6,6'-DIBROMO-[3,3']-BIPYRIDINE is used in the pharmaceutical industry for the development of new drugs. These complexes can possess unique biological activities, potentially leading to the discovery of novel therapeutic agents.
Used in Material Science:
In material science, 6,6'-DIBROMO-[3,3']-BIPYRIDINE is utilized in the synthesis of new materials with specific properties. The metal complexes derived from 6,6'-DIBROMO-[3,3']-BIPYRIDINE can be integrated into materials to enhance their performance in various applications, such as sensors, energy storage, and more.
Used in Chemical Research and Development:
6,6'-DIBROMO-[3,3']-BIPYRIDINE is a fundamental component in chemical research and development. Its unique properties and reactivity make it an essential tool for exploring new chemical reactions, synthesizing novel compounds, and advancing our understanding of chemical processes.
Check Digit Verification of cas no
The CAS Registry Mumber 147496-14-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,4,7,4,9 and 6 respectively; the second part has 2 digits, 1 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 147496-14:
(8*1)+(7*4)+(6*7)+(5*4)+(4*9)+(3*6)+(2*1)+(1*4)=158
158 % 10 = 8
So 147496-14-8 is a valid CAS Registry Number.
147496-14-8Relevant academic research and scientific papers
Pd-catalyzed oxidative homocoupling of arylboronic acids in WEPA: A sustainable access to symmetrical biaryls under added base and ligand-free ambient conditions
Appa, Rama Moorthy,Lakshmidevi, Jangam,Naidu, Bandameeda Ramesh,Venkateswarlu, Katta
, (2021/01/11)
Symmetrical and unsymmetrical biaryls comprises a diverse class of biologically eloquent organic compounds. We herein report, a quick and eco-friendly protocol for the synthesis of biaryls by an oxidative (aerobic) homocoupling of arylboronic acids (ABAs) using Pd(OAc)2 in water extract of pomogranate ash (WEPA) as an efficient agro-waste(bio)-derived aqueous (basic) media. The reactions were executed at ambient aerobic conditions in the absence of external base and ligand to result symmetrical biaryls in excellent yields. The use of renewable media with an effective exploitation of waste, short reaction times, excellent yields of products, easy separation of the products, unnecessating the external base, oxidant, ligand or volatile organic solvents and ambient reaction conditions are the vital insights of the present protocol.
A shape-persistent macrocycle with two opposing 2,2':6',2'-Terpyridine units
Lehmann, Uwe,Dieter Schlueter
, p. 3483 - 3487 (2007/10/03)
The synthesis reported here of the shape-persistent macrocycle 9 with two opposing terpyridine units, and with pendant flexible chains for solubility reasons, was achieved by Suzuki cross-coupling of two 'half-cycles', the bisboronic acid ester 7 and its diiodo counterpart 8. Cycle 9 was obtained on a 100 mg scale in a yield of 20%. It was characterized by FAB mass spectrometry and 1H and 13C NMR spectroscopy. Cycle 9 is the first shape-persistent cycle containing terpyridine units that is larger than cyclosexipyridine. An improved synthesis of the important building block dibromoterpyridine 12 is also presented.
