147503-39-7Relevant articles and documents
Directing the Solid-State Organization of Racemates via Structural Mutation and Solution-State Assembly Processes
Kulkarni, Chidambar,Berrocal, José Augusto,Lutz, Martin,Palmans, Anja R. A.,Meijer
supporting information, p. 6302 - 6309 (2019/04/25)
Chirality plays a central role in biomolecular recognition and pharmacological activity of drugs and can even lead to new functions such as spin filters. Although there have been significant advances in understanding and controlling the helical organizati
Organocatalytic Knoevenagel condensation by chiral: C 2-symmetric tertiary diamines
Gu, Xiaoyu,Tang, Yan,Zhang, Xiang,Luo, Zinbin,Lu, Hongfei
supporting information, p. 6580 - 6583 (2016/08/09)
The efficient Knoevenagel condensation catalyzed by (1S,2S)-1,2-diaminocyclohexane derivatives is presented and investigated. Various aliphatic aldehydes undergo condensation with active methylene compounds to yield the corresponding products in high yields. α-Branched aldehydes were found to be efficiently converted to the corresponding enantiomerically enriched products by using these chiral tertiary diamine catalysts.
Synthesis of Chiral Cobalt Complexes with Planoid-Tetradentate Ligand System
Haerter, Ralph,Weymuth, Christophe,Scheffold, Rolf,Engel, Peter,Linden, Anthony
, p. 353 - 371 (2007/10/02)
The synthesis of a series of Cbl-related, achiral Co(III) complexes 9a-c as well as enantiomerically pure, C2-symmetric Co(III) complexes 15 and 18, is reported (Schemes 3, 5, and 7).The crystal structures of 9c and 15 were determined.Complex 18 acts as an enantioselective catalyst in the isomerization of 1,4-epiperoxides to hydroxycycloalkenones.
