147513-93-7

Basic information

• Product Name: cone-25,26,27,28-tetrapropoxycalix{4}arene-tricarbonylchromium
• CAS NO: 147513-93-7
• Molecular Weight: 728.846
• Mol File: 147513-93-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cone-25,26,27,28-tetrapropoxycalix{4}arene-tricarbonylchromium(CAS DataBase Reference)
• NIST Chemistry Reference: cone-25,26,27,28-tetrapropoxycalix{4}arene-tricarbonylchromium(147513-93-7)
• EPA Substance Registry System: cone-25,26,27,28-tetrapropoxycalix{4}arene-tricarbonylchromium(147513-93-7)

Safety Data

• Hazardous Substances Data: 147513-93-7(Hazardous Substances Data)

Upstream product

• 140862-52-8 25,26,27,28-tetrapropyloxycalix[4]arene 
• 199620-14-9 chromium⁽⁰⁾ hexacarbonyl 

Downstream Products

• 10025-73-7 chromium(III) chloride 
• 140862-52-8 25,26,27,28-tetrapropyloxycalix[4]arene 

Relevant articles and documents

Syntheses and Spectral Characterizations of Tricarbonylchromium Complexes of Calixarenes

The 1:1 arene-tricarbonylchromium complexes were synthesized for the first time from four conformational isomers of 25,26,27,28-tetrapropoxycalixarene (14Pr) and Cr(CO)6.The 1:2, 1:3 and 1:4 complexes of cone-14Pr were also synthesized by increasing the ratio of Cr(CO)6 against cone-14Pr.The 1:2 complex was a mixture of two compounds, which were identified as distal and proximal isomers of cone-14Pr*2Cr(CO)3.The relative stability of the 1:1 complex was estimated via its oxidation by CuCl2.The pseudo-first-order rate constants appeared to be in the order of 1,3-alternate-14Pr > 1,2-alternate-14Pr > cone-14Pr > 2,6-dimethylanisole.The results indicate that the 14r*Cr(CO)3 complexes are less stable than the corresponding monomeric complex.The 1:1 complexes with partial-cone-14Pr and 1,2-alternate-14Pr were demonstrated to be a pair of racemates by 1H NMR spectroscopy using a chiral shift reagent (Pirkle's reagent).