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14752-61-5

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14752-61-5 Usage

Description

1-Pentynyl iodide, also known as 1-Pentyne iodide, is a chemical compound characterized by the molecular formula C5H7I. It is a colorless to pale yellow liquid that serves as a reagent in organic synthesis and as a building block for the production of various chemical compounds. 1-PENTYNYL IODIDE is instrumental in the preparation of alkynes, which are extensively utilized in the pharmaceutical and chemical industries. Its role in the construction of carbon-carbon and carbon-nitrogen bonds in organic synthesis is particularly noteworthy. However, due to its hazardous nature, 1-Pentynyl iodide is toxic if ingested or inhaled and can cause skin and eye irritation, necessitating careful handling and adherence to proper safety precautions.

Uses

Used in Organic Synthesis:
1-Pentynyl iodide is used as a reagent in organic synthesis for its ability to facilitate the formation of carbon-carbon and carbon-nitrogen bonds, which are crucial in the creation of complex organic molecules.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, 1-Pentynyl iodide is used as a building block for the synthesis of alkynes, which are key components in the development of various pharmaceutical compounds.
Used in Chemical Industry:
Similarly, in the chemical industry, 1-Pentynyl iodide is employed in the preparation of alkynes, contributing to the synthesis of a wide range of chemical products.
Safety Precautions:
Given its hazardous nature, 1-Pentynyl iodide requires careful handling. It is essential to follow proper safety precautions and handling procedures to minimize the risk of ingestion, inhalation, or skin and eye contact, which can lead to adverse health effects.

Check Digit Verification of cas no

The CAS Registry Mumber 14752-61-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,7,5 and 2 respectively; the second part has 2 digits, 6 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 14752-61:
(7*1)+(6*4)+(5*7)+(4*5)+(3*2)+(2*6)+(1*1)=105
105 % 10 = 5
So 14752-61-5 is a valid CAS Registry Number.
InChI:InChI=1/C5H7I/c1-2-3-4-5-6/h2-3H2,1H3

14752-61-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-Pentynyl Iodide

1.2 Other means of identification

Product number -
Other names 1-Iodo-1-pentyne

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:14752-61-5 SDS

14752-61-5Relevant articles and documents

Diastereoselective Addition of Prochiral Nucleophilic Alkenes to α-Chiral N-Sulfonyl Imines

Ando, Kaori,Fettinger, James,Gutierrez, David A.,Houk, K. N.,Shaw, Jared T.

supporting information, p. 1164 - 1168 (2022/02/14)

The Lewis-acid-promoted addition of prochiral E- and Z-allyl nucleophiles to chiral α-alkoxy N-tosyl imines is described. Alkene geometry is selectively transferred to the newly formed carbon-carbon bond, resulting in stereochemical control of C1, C2, and C3 of the resulting 2-alkoxy-3-N-tosyl-4-alkyl-5-hexene products. A computational analysis to elucidate the high selectivity is also presented. This methodology was employed in the synthesis of two naturally occurring isomers of clausenamide.

Improved syntheses of methyl (14E)- and (14Z)-dehydrocrepenynate: Key intermediates in plant and fungal polyacetylene biosynthesis

Zhu, Lizhi,Minto, Robert E.

, p. 3803 - 3805 (2007/10/03)

Efficient syntheses of the (14E)- and (14Z)-isomers of methyl dehydrocrepenynate have been achieved. The key steps involve Pd-catalyzed cross-coupling reactions furnishing the C=C double bonds between C14 and C15, followed by Wittig reactions to construct the (Z)-alkene at C9. High overall yields and stereoselectivities were achieved for both isomers.

Terminal 1-halo and 1-pseudohalo-1-alkynes via Bis(trimethylsilyl)peroxide (BTMSPO) promoted Umpolung transfer of halides and pseudohalides

Casarini,Dembech,Reginato,Ricci,Seconi

, p. 2169 - 2170 (2007/10/02)

Reaction of terminal acetylenes with readily available and inexpensive copper and zinc halides and pseudo-halides and BTMSPO has been found to be an effective and general route for obtaining, in the absence of bases and under mild conditions, 1-halo and 1-pseudohalo-1-alkynes in generally good yields.

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