147631-19-4

Basic information

• Product Name: (CH₃)3CGe(NHCH₂CH₂)3N
• Synonyms: (CH₃)3CGe(NHCH₂CH₂)3N
• CAS NO: 147631-19-4
• Molecular Weight: 272.917
• Mol File: 147631-19-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (CH₃)3CGe(NHCH₂CH₂)3N(CAS DataBase Reference)
• NIST Chemistry Reference: (CH₃)3CGe(NHCH₂CH₂)3N(147631-19-4)
• EPA Substance Registry System: (CH₃)3CGe(NHCH₂CH₂)3N(147631-19-4)

Safety Data

• Hazardous Substances Data: 147631-19-4(Hazardous Substances Data)

Upstream product

• 147631-20-7 (CH₃)3CGe(NCH₃CH₂CH₂)3N 
• 4097-89-6 2,2',2''-triaminotriethylamine 

Downstream Products

• 76228-29-0 (CH₃)3CGe(OCH₂CH₂)3N 
• 4097-89-6 2,2',2''-triaminotriethylamine 
• 65604-89-9 tris[2-(methylamino)ethyl]amine 

Relevant articles and documents

Synthesis and interconversions of azagermatranes

The syntheses of the first examples of the title compounds, namely, ZGe(NRCH2CH2)3N (4, R = H, Z = Me; 5, R = Me, Z = Me; 6, R = H, Z = t-Bu; 7, R = Me, Z = t-Bu; 8, R = Me, Z = NMe2) are reported. Syntheses of the new compounds MeGe(NMe2)3 and t-BuGe(NMe2)3 and an improved synthesis of Ge(NMe2)4 are also recorded. The azagermatranes 5 and 7 are transformed to 4 and 6, respectively, in the presence of (H2NCH2CH2)3N. This reaction was not found to be reversible, however. Azagermatranes 4 or 5 and 6 or 7 in the presence of (HOCH2CH2)3N easily react to give MeGe(OCH2CH2)3N and t-BuGe(OCH2CH2)3N, respectively. Because of steric factors, one or more of compounds 6-8 may display weakened transannular Ge←N bonding or even an absence of this bonding.