147744-94-3Relevant academic research and scientific papers
Diphenylsilylene
Moiseev, Andrey G.,Leigh, William J.
, p. 14442 - 14443 (2008/02/02)
Lamp or pulsed laser photolysis of 1,1,3,3-tetramethyl-2,2-diphenyl-1,2,3-trisilacycloheptane affords diphenylsilylene (SiPh2) with significantly higher selectivity than that reported previously from other SiPh2 precursors, allowing
Electroreductive synthesis of oligosilanes and polysilanes with ordered sequences
Ishifune, Manabu,Kashimura, Shigenori,Kogai, Yasumichi,Fukuhara, Yasuyoshi,Kato, Tomo,Bu, Hang-Bom,Yamashita, Natsuki,Murai, Yoshibiro,Murase, Hiroaki,Nishida, Ryoichi
, p. 26 - 31 (2007/10/03)
The stepwise elongation of Si-Si or Si-Ge chain was achieved by the electroreductive cross-coupling reaction of chlorohydrosilanes with dichlorooligosilanes using magnesium electrodes. The electroreductive cross-coupling reaction of chlorodimethylsilane (
Synthesis of novel polysilynes and branched polysilanes
Uhlig, Wolfram
, p. 703 - 710 (2007/10/03)
The reductive coupling of halogenated oligosilanes with potassium-graphite leads to novel polysilynes and branched polysilanes. The ratio of quaternary silicon atoms, monoorganosilyl- and diorganosilylgroups in the polymers can be modified by variation in the structure of the starting materials. In this way the properties of the preceramic polymers (molecular weights, solubility, content of carbon, degree of cross-linking) are influenced. The compounds are characterized by 29Si NMR spectroscopy.
Decomposition of bis( silyldiazomethyl) polysilanes: formation of polysilabicyclo(l.m.n)alkane derivatives
Ando, Wataru,Sugiyama, Mitsuru,Suzuki, Tomohisa,Kato, Chikako,Arakawa, Yusuke,Kabe, Yoshio
, p. 99 - 112 (2007/10/02)
The photolysis of bis(trimethylsilyldiazomethyl)disilane (4a) in tert-butyl alcohol provided the tert-butyl alcohol adducts S, 6, 7, 8 and 9.The structures of these products revealed the stepwise formation of asymmetric silenes as intermediates.Gas-phase
