53549-17-0Relevant academic research and scientific papers
Diphenylsilylene
Moiseev, Andrey G.,Leigh, William J.
, p. 14442 - 14443 (2008/02/02)
Lamp or pulsed laser photolysis of 1,1,3,3-tetramethyl-2,2-diphenyl-1,2,3-trisilacycloheptane affords diphenylsilylene (SiPh2) with significantly higher selectivity than that reported previously from other SiPh2 precursors, allowing
Electroreductive synthesis of oligosilanes and polysilanes with ordered sequences
Ishifune, Manabu,Kashimura, Shigenori,Kogai, Yasumichi,Fukuhara, Yasuyoshi,Kato, Tomo,Bu, Hang-Bom,Yamashita, Natsuki,Murai, Yoshibiro,Murase, Hiroaki,Nishida, Ryoichi
, p. 26 - 31 (2007/10/03)
The stepwise elongation of Si-Si or Si-Ge chain was achieved by the electroreductive cross-coupling reaction of chlorohydrosilanes with dichlorooligosilanes using magnesium electrodes. The electroreductive cross-coupling reaction of chlorodimethylsilane (
Decomposition of bis( silyldiazomethyl) polysilanes: formation of polysilabicyclo(l.m.n)alkane derivatives
Ando, Wataru,Sugiyama, Mitsuru,Suzuki, Tomohisa,Kato, Chikako,Arakawa, Yusuke,Kabe, Yoshio
, p. 99 - 112 (2007/10/02)
The photolysis of bis(trimethylsilyldiazomethyl)disilane (4a) in tert-butyl alcohol provided the tert-butyl alcohol adducts S, 6, 7, 8 and 9.The structures of these products revealed the stepwise formation of asymmetric silenes as intermediates.Gas-phase
