53549-17-0Relevant articles and documents
Diphenylsilylene
Moiseev, Andrey G.,Leigh, William J.
, p. 14442 - 14443 (2008/02/02)
Lamp or pulsed laser photolysis of 1,1,3,3-tetramethyl-2,2-diphenyl-1,2,3-trisilacycloheptane affords diphenylsilylene (SiPh2) with significantly higher selectivity than that reported previously from other SiPh2 precursors, allowing
Decomposition of bis( silyldiazomethyl) polysilanes: formation of polysilabicyclo(l.m.n)alkane derivatives
Ando, Wataru,Sugiyama, Mitsuru,Suzuki, Tomohisa,Kato, Chikako,Arakawa, Yusuke,Kabe, Yoshio
, p. 99 - 112 (2007/10/02)
The photolysis of bis(trimethylsilyldiazomethyl)disilane (4a) in tert-butyl alcohol provided the tert-butyl alcohol adducts S, 6, 7, 8 and 9.The structures of these products revealed the stepwise formation of asymmetric silenes as intermediates.Gas-phase