14775-15-6Relevant academic research and scientific papers
Hydrostannation of C-C multiple bonds with Bu3SnH prepared in situ from Bu3SnCl and Et3SiH in the presence of Lewis acid catalysts
Gevorgyan, Vladimir,Liu, Jian-Xiu,Yamamoto, Yoshinori
, p. 37 - 38 (1998)
A number of alkynes 5, allene 11 and alkene 13 smoothly underwent hydrostannation with tributyltin hydride 1, prepared in situ from tributylchlorostannane 6 and triethylsilane 7 in the presence of catalytic amounts of Lewis acids.
Thermolysis of Cp(CO)nM-CH(CH3)C6H5 (n = 2, M = Fe, Ru; n = 3, M = Mo, W). Some vertical trends in transition metal-alkyl bond dissociation energies
Mancuso, Curt,Halpern, Jack
, p. C8 - C11 (1992)
Elucidation of the products and kinetics of thermolysis of the series of compounds, Cp(CO)nM-CH(CH3)C6H5 (n = 2, M = Fe, Ru; n = 3, M = Mo, W), in benzene, in the absence and presence of free radical traps, yielded the following values of ΔH
Illuminating Stannylation
Sakamoto, Kyoka,Nagashima, Yuki,Wang, Chao,Miyamoto, Kazunori,Tanaka, Ken,Uchiyama, Masanobu
supporting information, p. 5629 - 5635 (2021/05/04)
We have developed photoboosted stannylation reactions of terminal alkynes (linear-selective hydrostannylation) and fluoroarenes (defluorostannylation), in which the stannyl anion is photoexcited to an excited triplet (T1) stannyl diradical species. This u
Lewis acid-catalyzed hydrometalation and carbometalation of unactivated alkynes
Asao, Naoki,Yamamoto, Yoshinori
, p. 1071 - 1087 (2007/10/03)
Hydrosilylation, hydrostannation, carbosilylation, and carbostannation of unactivated alkynes with organosilanes, or organostannanes proceed effectively in the presence of catalytic amounts of Lewis acids to produce the corresponding vinylsilyl or vinylst
Intramolecular assistance of electron transfer. Oxidative cleavage of the carbon-tin bond of tetraalkylstannanes
Yoshida, Jun-Ichi,Izawa, Mitsuhiko
, p. 9361 - 9365 (2007/10/03)
Experimental and theoretical studies of intramolecular assistance by carbonyl groups and heteroatoms in the electron transfer driven cleavage of the carbon-tin bond of tetraalkylstannanes has been carried out. Carbonyl groups and heteroatoms (oxygen and n
