147834-30-8Relevant articles and documents
Controlled Reaction of Molecular Oxygen with to form the Mixed Phosphine-Phosphine Oxide Complex and the Bis(phosphine oxide) Complex
Godfrey, Stephen M.,McAuliffe, Charles A.,Ndifon, Peter T.,Pritchard, Robin G.
, p. 3373 - 3378 (1993)
When a preformed solution of in pentane at -40 deg C under argon was allowed to warm to room temperature, specific oxidation of one phosphine occurred and an almost quantitative yield of the mixed phosphine-phosphine oxide complex was obtained; when the same procedure is followed under dry dioxygen the oxidation of both phosphines occurs and is obtained in almost quantitative yield.X-Ray crystallography showed both of these complexes to be pseudo-tetrahedral monomers, and represents the first example of a mixed phosphine-phosphine oxide complex of manganese to be reported.
The Reaction of Bromo- and Iodo-phosphoranes with Unactivated Coarse Grain Manganese Metal Powder to Yield and n> (X = Br or I) by Insertion of Mn into the P-X Bond. The Crystal Structure of
Godfrey, Stephen M.,McAuliffe, Charles A.,Pritchard, Robin G.
, p. 371 - 376 (2007/10/02)
The novel reaction of crude manganese metal powder with dibromo- and diiodo-phosphoranes, R3PX2, has been studied.Reaction of the phosphoranes R3PI2 (R = phenyl or substituted aryl) with manganese allows insertion of the metal into P-X bonds and gives the
