154155-37-0

Basic information

• Product Name: MnI₂(OPPh₂Me)(PPh₂Me)
• CAS NO: 154155-37-0
• Molecular Weight: 725.186
• Mol File: 154155-37-0.mol

Chemical Properties

• CAS DataBase Reference: MnI₂(OPPh₂Me)(PPh₂Me)(CAS DataBase Reference)
• NIST Chemistry Reference: MnI₂(OPPh₂Me)(PPh₂Me)(154155-37-0)
• EPA Substance Registry System: MnI₂(OPPh₂Me)(PPh₂Me)(154155-37-0)

Safety Data

• Hazardous Substances Data: 154155-37-0(Hazardous Substances Data)

Upstream product

• 1486-28-8 diphenyl(methyl)phosphine 
• 147834-30-8 {MnI₂(P(C₆H₅)2CH₃)2} 

Relevant articles and documents

Controlled Reaction of Molecular Oxygen with to form the Mixed Phosphine-Phosphine Oxide Complex and the Bis(phosphine oxide) Complex

When a preformed solution of in pentane at -40 deg C under argon was allowed to warm to room temperature, specific oxidation of one phosphine occurred and an almost quantitative yield of the mixed phosphine-phosphine oxide complex was obtained; when the same procedure is followed under dry dioxygen the oxidation of both phosphines occurs and is obtained in almost quantitative yield.X-Ray crystallography showed both of these complexes to be pseudo-tetrahedral monomers, and represents the first example of a mixed phosphine-phosphine oxide complex of manganese to be reported.