147910-22-3

Upstream product

• 147910-18-7 [(R)-2-((2S,3S,4S,5S)-3-Benzyloxy-5-methoxy-4-methyl-tetrahydro-furan-2-yl)-2-methoxymethoxy-ethoxy]-tert-butyl-dimethyl-silane 
• 147910-19-8 (R)-2-((2S,3S,4S,5S)-3-Benzyloxy-5-methoxy-4-methyl-tetrahydro-furan-2-yl)-2-methoxymethoxy-ethanol 
• 100-39-0 benzyl bromide 
• 68907-47-1 methyl 4,6-O-benzylidene-2-deoxy-2-C-methyl-α-D-altro-pyranoside 
• 109958-35-2 (2R,4aR,6S,7S,8S,8aS)-8-Benzyloxy-6-methoxy-7-methyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine 
• 147910-17-6 (R)-1-((2R,3S,4S,5S)-3-Benzyloxy-5-methoxy-4-methyl-tetrahydro-furan-2-yl)-ethane-1,2-diol 

Downstream Products

• 147910-26-7 (E)-(1R,2S,5R)-5-((2S,3S,4S,5S)-3-Benzyloxy-5-methoxy-4-methyl-tetrahydro-furan-2-yl)-1-(4,4-dimethyl-4,5-dihydro-oxazol-2-yl)-5-methoxymethoxy-2,4-dimethyl-pent-3-en-1-ol 

Relevant academic research and scientific papers

Diastereoselective [2,3] Wittig rearrangement of carbohydrate-derived tertiary allylic ethers. 2. Synthesis of an advanced rapamycin intermediate fromD-glucose

The advanced rapamycin intermediate 26 has been prepared by an iterative sigmatropic sequence incorporating the diastereoselective [2,3] Wittig rearrangement of a D-glucofuranose-derived tertiary allylic ether.