14796-87-3Relevant academic research and scientific papers
Selective synthesis of 4-alkylidene-β-lactams and N,N′- diarylamidines from azides and aryloxyacetyl chlorides via a ketenimine-participating one-pot cascade process
Yang, Yun-Yun,Shou, Wang-Ge,Hong, Deng,Wang, Yan-Guang
, p. 3574 - 3577 (2008/09/20)
(Chemical Equation Presented) A one-pot cascade approach to 4-alkylidene-β-lactams and N,N-diarylamidines from aryl azides and aryloxyacetyl chlorides has been developed. The chemical outcome of the reaction can be controlled selectively by an appropriate choice of the stoichiometric ratio of different substrates and reagents. The products should find use in pharmaceutical discovery, especially in the development of new antimicrobial agents against multidrug-resistant pathogens.
Complexes of N-aryltriphenylphosphinimines with mercury(II) halides
Braun, Thomas P.,Gutsch, Paul A.,Zimmer, Hans
, p. 858 - 862 (2007/10/03)
The synthesis IR and 31P NMR spectra of the complexes of various N-aryltriphenylphosphinimines with some mercury dihalides as well as the corresponding phosphonium salts are reported It is shown by an X-ray crystal structure analysis of the complex of the unsubstituted phosphinimine with HgCl2 that in the solid state these complexes form dimers via two Hg...μ2 Cl...Hg bridges.
