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Low price with good quality 3-Chlorobenzenamine
Cas No: 108-42-9
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3-Chloroaniline (C.I. 37005)
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Benzenamine,3-chloro- cas:108-42-9
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USD $ 100.0-150.0 / Kilogram 1 Kilogram 1000 Metric Ton/Day Wuhan Monad Medicine Tech Co.,LTD Contact Supplier

108-42-9 Usage

Fire Hazard

3-Chloroaniline is combustible.

General Description

Colorless to light amber liquid with a sweet odor.

Chemical Properties

clear pale yellow to brown liquid

Air & Water Reactions

Sensitive to prolonged exposure to air and light and tends to darken during storage. Insoluble in water.

Uses

3-Chlorobenzenamine is used in the synthesis of pyrimidoazepine analogs as serotonin 5-HT2A and 5-HT2C receptor ligands for the treatment of obesity. Also used in the synthesis of novel COX-2 inhibito rs.

Reactivity Profile

3-Chloroaniline is incompatible with acids, acid chlorides, acid anhydrides, chloroformates and strong oxidizing agents.
InChI:InChI=1/C6H6ClN.ClH/c7-5-2-1-3-6(8)4-5;/h1-4H,8H2;1H

108-42-9 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Sigma-Aldrich (35824)  3-Chloroaniline  PESTANAL®, analytical standard 108-42-9 35824-1G 215.28CNY Detail
Alfa Aesar (A12019)  3-Chloroaniline, 99%    108-42-9 10000g 5746.0CNY Detail
Alfa Aesar (A12019)  3-Chloroaniline, 99%    108-42-9 500g 444.0CNY Detail
Alfa Aesar (A12019)  3-Chloroaniline, 99%    108-42-9 100g 217.0CNY Detail

108-42-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-Chloroaniline

1.2 Other means of identification

Product number -
Other names Orange GC Base

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:108-42-9 SDS

108-42-9Synthetic route

3-Chloronitrobenzene
121-73-3

3-Chloronitrobenzene

3-chloro-aniline
108-42-9

3-chloro-aniline

Conditions
ConditionsYield
With 2 weight% platinum on carbon; ethanol at 100℃; under 7500.75 Torr; for 8h; Autoclave;100%
With hydrogen In ethanol at 20℃; under 7500.75 Torr; for 8h; Catalytic behavior; Sealed tube;100%
With hydrazine hydrate In ethanol; water at 80℃; for 1h; chemoselective reaction;100%
m,p-dichloroaniline
95-76-1

m,p-dichloroaniline

3-chloro-aniline
108-42-9

3-chloro-aniline

Conditions
ConditionsYield
100%
2,3-dichloroaniline
608-27-5

2,3-dichloroaniline

3-chloro-aniline
108-42-9

3-chloro-aniline

Conditions
ConditionsYield
100%
palladium
7440-05-3

palladium

2,4,5-trichloroaniline
636-30-6

2,4,5-trichloroaniline

3-chloro-aniline
108-42-9

3-chloro-aniline

Conditions
ConditionsYield
With hydrogenchloride; potassium iodide98.2%
1-azido-3-chlorobenzene
3296-06-8

1-azido-3-chlorobenzene

3-chloro-aniline
108-42-9

3-chloro-aniline

Conditions
ConditionsYield
With samarium diiodide In tetrahydrofuran for 2h; Ambient temperature;98%
Stage #1: 1-azido-3-chlorobenzene With hydrazine hydrate for 0.166667h; Inert atmosphere;
Stage #2: for 10h; Irradiation; chemoselective reaction;
90%
With zinc(II) tetrahydroborate In 1,2-dimethoxyethane for 3.5h; Ambient temperature;89%
3,4,5-trichloroaniline
634-91-3

3,4,5-trichloroaniline

A

3-chloro-aniline
108-42-9

3-chloro-aniline

B

3,5-Dichloroaniline
626-43-7

3,5-Dichloroaniline

Conditions
ConditionsYield
A 97.9%
B n/a
2,3-dichloroaniline
608-27-5

2,3-dichloroaniline

1,2-dichloro-benzene
95-50-1

1,2-dichloro-benzene

m,p-dichloroaniline
95-76-1

m,p-dichloroaniline

3-chloro-aniline
108-42-9

3-chloro-aniline

Conditions
ConditionsYield
With HI; hydrogen iodide96.5%
concentrated aqueous sodium hydroxide

concentrated aqueous sodium hydroxide

2,3-dichloroaniline
608-27-5

2,3-dichloroaniline

phenol
108-95-2

phenol

3-chloro-aniline
108-42-9

3-chloro-aniline

Conditions
ConditionsYield
With hydrogen; palladium/charcoal In tantalum; water; toluene96%
3-iodochlorobenzene
625-99-0

3-iodochlorobenzene

3-chloro-aniline
108-42-9

3-chloro-aniline

Conditions
ConditionsYield
With copper(I) oxide; ammonium hydroxide; C17H14N2O3; potassium hydroxide In ethanol at 60℃; for 24h; Schlenk technique; Inert atmosphere;96%
With ammonium hydroxide; potassium phosphate; 1-(5,6,7,8-tetrahydroquinolin-8-yl)-2-methylpropan-1-one; copper(I) bromide In dimethyl sulfoxide at 25℃; for 24h; Inert atmosphere; Sealed tube;90%
With copper(l) iodide; tetra(n-butyl)ammonium hydroxide; ammonia In water at 25℃; for 24h; Inert atmosphere; Sealed tube; chemoselective reaction;89%
1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

3-chloro-aniline
108-42-9

3-chloro-aniline

Conditions
ConditionsYield
With copper(I) oxide; ammonium hydroxide In 1-methyl-pyrrolidin-2-one at 80℃; for 15h;93%
With ammonium hydroxide; potassium phosphate; 1-(5,6,7,8-tetrahydroquinolin-8-yl)-2-methylpropan-1-one; copper(I) bromide In dimethyl sulfoxide at 110℃; for 24h; Inert atmosphere; Sealed tube;93%
With ammonium hydroxide; copper(l) iodide; 2,2-[μ-(N,N'-piperazindiyl)dimethyl]-bis(4,6-di-tert-butyl-phenol) In water at 120℃; for 12h;85%
2,2,2-trichloroethyl N-(m-chlorophenyl)carbamate

2,2,2-trichloroethyl N-(m-chlorophenyl)carbamate

3-chloro-aniline
108-42-9

3-chloro-aniline

Conditions
ConditionsYield
With indium; ammonium chloride In ethanol for 2.5h; Heating;86%
(3-chlorophenyl)magnesium bromide
36229-42-2

(3-chlorophenyl)magnesium bromide

3-chloro-aniline
108-42-9

3-chloro-aniline

Conditions
ConditionsYield
Stage #1: (3-chlorophenyl)magnesium bromide With zinc(II) chloride In tetrahydrofuran at -3 - 20℃; Inert atmosphere;
Stage #2: With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; dimethylsulfide; acetone oxime-o-p-benzenesulfonic ester; copper(ll) bromide In tetrahydrofuran at 20℃; for 1.5h; Inert atmosphere;
Stage #3: With hydrogenchloride; water In tetrahydrofuran at 20℃; for 4h; Inert atmosphere;
85%
Multi-step reaction with 3 steps
1: tetrahydrofuran / -3 - 20 °C / Inert atmosphere
2: copper(l) cyanide / tetrahydrofuran / 1.5 h / 20 °C / Inert atmosphere
3: hydrogenchloride / water; tetrahydrofuran / 20 °C
View Scheme
Multi-step reaction with 2 steps
1.1: tetrahydrofuran / -5 - 20 °C / Inert atmosphere
2.1: acetone O-(2,4,6-trimethylphenylsulfonyl)oxime; triphenylphosphine / tetrahydrofuran / 0.08 h / 20 °C / Inert atmosphere
2.2: 20 °C / Inert atmosphere
View Scheme
Multi-step reaction with 3 steps
1: tetrahydrofuran / 0.17 h / 10 °C / Inert atmosphere
2: copper(l) cyanide / tetrahydrofuran / 0.5 h / 20 °C / Inert atmosphere
3: water; hydrogenchloride / 24 h / 20 °C / Inert atmosphere
View Scheme
Multi-step reaction with 3 steps
1: tetrahydrofuran / 0.17 h / 10 °C / Inert atmosphere
2: copper(l) cyanide / tetrahydrofuran / 0.5 h / 20 °C / Inert atmosphere
3: water; hydrogenchloride / 24 h / 20 °C / Inert atmosphere
View Scheme
2,4,5-trichloroaniline
636-30-6

2,4,5-trichloroaniline

3-chloro-aniline
108-42-9

3-chloro-aniline

Conditions
ConditionsYield
With hydrogenchloride In water84.1%
3-Chloroacetanilide
588-07-8

3-Chloroacetanilide

A

N-ethyl-3-chloroaniline
15258-44-3

N-ethyl-3-chloroaniline

B

3-chloro-aniline
108-42-9

3-chloro-aniline

Conditions
ConditionsYield
With dihydridocarbonyl(1,1,1-tris(diphenylphosphinomethyl)ethane)ruthenium(II) complex; boron trifluoride diethyl etherate; hydrogen; toluene-4-sulfonic acid In tetrahydrofuran at 120℃; under 38002.6 Torr; for 16h; Glovebox; Autoclave; Inert atmosphere;A 84%
B n/a
With [bis(2-methylallyl)cycloocta-1,5-diene]ruthenium(II); formic acid; bis(trifluoromethanesulfonyl)amide; triethylamine; [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine] In dibutyl ether at 130℃; for 24h;A n/a
B 76%
With C18H32ClIrO2P2; tris(pentafluorophenyl)borate; hydrogen; sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate In toluene at 120℃; under 38002.6 Torr; for 24h; Overall yield = 84 %; Overall yield = 87 %Chromat.; chemoselective reaction;
2-(trimethylsilyl)-5-chloronitrobenzene
78627-94-8

2-(trimethylsilyl)-5-chloronitrobenzene

3-chloro-aniline
108-42-9

3-chloro-aniline

Conditions
ConditionsYield
With hydrogenchloride; tin for 15h; Heating;83%
t-butyl 3-chlorophenylcarbamate
5330-63-2

t-butyl 3-chlorophenylcarbamate

3-chloro-aniline
108-42-9

3-chloro-aniline

Conditions
ConditionsYield
With methanol; oxalyl dichloride at 20℃; for 2h;83%
3-Chloronitrobenzene
121-73-3

3-Chloronitrobenzene

A

aniline
62-53-3

aniline

B

3-chloro-aniline
108-42-9

3-chloro-aniline

C

3,3'-dichloroazobenzene
15426-14-9, 106131-20-8, 106131-24-2

3,3'-dichloroazobenzene

D

3,3'-dichloroazoxybenzene
139-24-2, 71297-98-8

3,3'-dichloroazoxybenzene

Conditions
ConditionsYield
With bis(acetylacetonato)palladium(II); phosphorus; hydrogen In N,N-dimethyl-formamide; benzene at 50℃; under 1520.1 Torr; for 1.75h; Catalytic behavior; Time; chemoselective reaction;A 9.4%
B 81.4%
C n/a
D n/a
3-Chloronitrobenzene
121-73-3

3-Chloronitrobenzene

A

aniline
62-53-3

aniline

B

3-chloro-aniline
108-42-9

3-chloro-aniline

Conditions
ConditionsYield
With Rh/Al2O3; hydrogen In water; toluene at 80℃; under 30003 Torr; for 24h; Reagent/catalyst;A 17%
B 81%
With isopropyl alcohol; sodium hydroxide for 12h; Inert atmosphere; Reflux; chemoselective reaction;A n/a
B 76%
With hydrogen; nickel-chromium catalyst In isopropyl alcohol at 49.9℃; under 760 Torr;
3-chlorobenzamide
618-48-4

3-chlorobenzamide

3-chloro-aniline
108-42-9

3-chloro-aniline

Conditions
ConditionsYield
With sodium hydroxide; benzyltrimethylazanium tribroman-2-uide In water for 2h; Ambient temperature;79%
3-chlorobenzoate
535-80-8

3-chlorobenzoate

3-chloro-aniline
108-42-9

3-chloro-aniline

Conditions
ConditionsYield
Stage #1: 3-chlorobenzoate With trifluorormethanesulfonic acid; trimethylsilylazide In chloroform at 90℃; for 0.055h; Schmidt Reaction; Flow reactor;
Stage #2: With water In methanol; chloroform at 20℃; Schmidt Reaction; Flow reactor;
79%
With thionyl chloride; hydroxylamine-O-sulfonic acid 1) 1h, reflux, 2) toluene, 2h, reflux; Yield given. Multistep reaction;
3-Chloronitrobenzene
121-73-3

3-Chloronitrobenzene

A

3-chloro-aniline
108-42-9

3-chloro-aniline

B

3,3'-dichloroazobenzene
15426-14-9, 106131-20-8, 106131-24-2

3,3'-dichloroazobenzene

C

3,3'-dichloroazoxybenzene
139-24-2, 71297-98-8

3,3'-dichloroazoxybenzene

Conditions
ConditionsYield
With hydrazine hydrate; nickel(II) nitrate; zinc In tert-butyl alcohol for 0.333333h; Heating;A 5%
B 6 % Chromat.
C 78%
With hydrazine hydrate; nickel(II) nitrate; zinc In ethanol for 3h; Heating;A 15 % Chromat.
B 12%
C 43%
indole
120-72-9

indole

2-phenyl-1,2,3,4-tetrahydroisoquinoline
3340-78-1

2-phenyl-1,2,3,4-tetrahydroisoquinoline

3-Chloronitrobenzene
121-73-3

3-Chloronitrobenzene

A

1-(1H-indol-3-yl)-2-phenyl-1, 2, 3, 4-tetrahydroisoquinoline

1-(1H-indol-3-yl)-2-phenyl-1, 2, 3, 4-tetrahydroisoquinoline

B

3-chloro-aniline
108-42-9

3-chloro-aniline

Conditions
ConditionsYield
With Co(dmgH)2Cl2; Eosin Y In water; acetonitrile at 20℃; for 48h; Inert atmosphere; Irradiation; Sealed tube;A 78%
B 90 %Spectr.
3-Chlorostyrene
2039-85-2

3-Chlorostyrene

3-chloro-aniline
108-42-9

3-chloro-aniline

Conditions
ConditionsYield
With methanesulfonic acid; trimethylsilylazide In tetrachloromethane at 80℃; for 4h;76%
3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

3-chloro-aniline
108-42-9

3-chloro-aniline

Conditions
ConditionsYield
With copper(I) oxide; ammonium hydroxide; air In methanol at 20℃; for 18h;74%
With copper(I) oxide; ammonium hydroxide; oxygen; sodium hydroxide In water at 25℃; for 15h;70%
1-azido-3-chlorobenzene
3296-06-8

1-azido-3-chlorobenzene

tributylgermanium hydride
998-39-0

tributylgermanium hydride

A

5-chloro-2-tributylgermylaniline

5-chloro-2-tributylgermylaniline

B

3-chloro-2-tributylgermylaniline

3-chloro-2-tributylgermylaniline

C

3-chloro-aniline
108-42-9

3-chloro-aniline

Conditions
ConditionsYield
With tributylgermanium hydride; thiophenol In toluene for 0.5h; Heating;A 7%
B 5%
C 73%
2-(3-chlorophenoxy)propanamide

2-(3-chlorophenoxy)propanamide

3-chloro-aniline
108-42-9

3-chloro-aniline

Conditions
ConditionsYield
With potassium hydroxide In dimethyl sulfoxide at 140℃; for 6h; Green chemistry;71%
ammonium hydroxide
1336-21-6

ammonium hydroxide

3-iodochlorobenzene
625-99-0

3-iodochlorobenzene

3-chloro-aniline
108-42-9

3-chloro-aniline

Conditions
ConditionsYield
With copper(ll) sulfate pentahydrate; potassium phosphate tribasic heptahydrate; water; Sucrose In water at 90℃; for 15h; Catalytic behavior; Green chemistry;70%
1-(3-Chlor-anilino)-3-(3-chlor-phenylimino)-propen
25419-60-7

1-(3-Chlor-anilino)-3-(3-chlor-phenylimino)-propen

A

β-(m-Chloranilino)acrolein
51217-97-1

β-(m-Chloranilino)acrolein

B

3-chloro-aniline
108-42-9

3-chloro-aniline

Conditions
ConditionsYield
With water; sodium acetate; acetic acid In ethanol at 70℃; for 32.5h;A 52%
B 68%
chloroformic acid ethyl ester
541-41-3

chloroformic acid ethyl ester

3-chloro-aniline
108-42-9

3-chloro-aniline

(3-chlorophenyl) carbamic acid ethyl ester
2150-89-2

(3-chlorophenyl) carbamic acid ethyl ester

Conditions
ConditionsYield
With pyridine at 0℃; for 1h;100%
With sodium carbonate; benzene
With potassium carbonate In 1,4-dioxane for 2h; Heating;
With pyridine at 0 - 20℃;
chloroacetyl chloride
79-04-9

chloroacetyl chloride

3-chloro-aniline
108-42-9

3-chloro-aniline

2-chloro-N-(3-chlorophenyl)acetamide
2564-05-8

2-chloro-N-(3-chlorophenyl)acetamide

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 25℃;100%
With triethylamine In dichloromethane at 0 - 25℃;100%
In tetrahydrofuran at 20℃; for 18h;100%
3-chloro-aniline
108-42-9

3-chloro-aniline

diethyl 2-ethoxymethylenemalonate
87-13-8

diethyl 2-ethoxymethylenemalonate

2-(3-chlorophenylamino)methylenemalonic acid diethyl ester
3412-99-5

2-(3-chlorophenylamino)methylenemalonic acid diethyl ester

Conditions
ConditionsYield
In toluene at 110℃; for 24h;100%
In neat (no solvent) at 120℃; for 0.75h;98%
In ethanol for 3h; Reflux;91%
3,4-dimethoxy-benzaldehyde
120-14-9

3,4-dimethoxy-benzaldehyde

3-chloro-aniline
108-42-9

3-chloro-aniline

(3-Chloro-phenyl)-[1-(3,4-dimethoxy-phenyl)-meth-(E)-ylidene]-amine
82363-26-6

(3-Chloro-phenyl)-[1-(3,4-dimethoxy-phenyl)-meth-(E)-ylidene]-amine

Conditions
ConditionsYield
In toluene Heating;100%
2-isothiocyanatobenzylpyridinium bromide
109768-45-8

2-isothiocyanatobenzylpyridinium bromide

3-chloro-aniline
108-42-9

3-chloro-aniline

1-{2-[3-(3-Chloro-phenyl)-thioureido]-benzyl}-pyridinium; bromide
109768-52-7

1-{2-[3-(3-Chloro-phenyl)-thioureido]-benzyl}-pyridinium; bromide

Conditions
ConditionsYield
In methanol for 5h;100%
3-chloro-aniline
108-42-9

3-chloro-aniline

trifluoromethyl dihydro-1,4-dioxin-3-carbonyl chloride

trifluoromethyl dihydro-1,4-dioxin-3-carbonyl chloride

N-(3-chloro)phenyl-5,6-dihydro-2-trifluoromethyl-1,4-dioxin-3-carboxamide

N-(3-chloro)phenyl-5,6-dihydro-2-trifluoromethyl-1,4-dioxin-3-carboxamide

Conditions
ConditionsYield
Stage #1: trifluoromethyl dihydro-1,4-dioxin-3-carbonyl chloride With pyridine; polystyrene-bound 4-hydroxy-3-nitrobenzophenone In dichloromethane at 20℃; for 24h; Condensation;
Stage #2: 3-chloro-aniline With triethylamine In acetonitrile for 14h; Condensation; Heating;
100%
methanol
67-56-1

methanol

3-chloro-aniline
108-42-9

3-chloro-aniline

3-chloro-N,N-dimethylaniline
6848-13-1

3-chloro-N,N-dimethylaniline

Conditions
ConditionsYield
With C15H29IrN4(2+)*2I(1-) at 120℃; for 17h; Inert atmosphere; Schlenk technique; Sealed tube;100%
With tetrachloromethane; copper(ll) bromide at 180℃; for 6h; Inert atmosphere; Sealed tube;99%
With sulfuric acid at 200℃; for 16h;77%
With TiO2 supported nano-Pd(0.3) catalyst In water at 20℃; for 5h; Inert atmosphere; Irradiation; Green chemistry;65 %Chromat.
With zinc oxide-supported iridium catalyst at 150℃; under 3750.38 Torr; for 5h; Inert atmosphere;99 %Chromat.
1,4-dichlorophthalazine
4752-10-7

1,4-dichlorophthalazine

3-chloro-aniline
108-42-9

3-chloro-aniline

4-chloro-N-(3-chlorophenyl)phthalazin-1-amine

4-chloro-N-(3-chlorophenyl)phthalazin-1-amine

Conditions
ConditionsYield
In isopropyl alcohol at 100℃; for 1h;100%
With triethylamine In butan-1-ol at 100℃;
Stage #1: 1,4-dichlorophthalazine; 3-chloro-aniline In ethanol for 0.5h; Reflux;
Stage #2: With sodium hydroxide In ethanol; water at 20℃;
di-tert-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

3-chloro-aniline
108-42-9

3-chloro-aniline

t-butyl 3-chlorophenylcarbamate
5330-63-2

t-butyl 3-chlorophenylcarbamate

Conditions
ConditionsYield
In methanol at 100℃; for 6h;100%
Stage #1: 3-chloro-aniline With triethylamine In tetrahydrofuran; water at 20℃; for 0.0833333h;
Stage #2: di-tert-butyl dicarbonate In tetrahydrofuran; water at 0 - 20℃; for 6h;
100%
With 1,1'-hexane-1,6-diylbis(3-methylpyridinium)tetrachlorocobaltate(II) In neat (no solvent) at 20℃; for 1h;97%
bromobenzene
108-86-1

bromobenzene

3-chloro-aniline
108-42-9

3-chloro-aniline

3-chlorodiphenylamine
101-17-7

3-chlorodiphenylamine

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium (0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate In toluene at 90 - 110℃; for 11h; Buchwald-Hartwig reaction;100%
With pectin-stabilized copper nanoparticles In dimethyl sulfoxide at 110℃; for 2h;82%
3-chloro-aniline
108-42-9

3-chloro-aniline

1-azido-3-chlorobenzene
3296-06-8

1-azido-3-chlorobenzene

Conditions
ConditionsYield
With tert.-butylnitrite; trimethylsilylazide In acetonitrile at 0 - 20℃; for 1h;100%
Stage #1: 3-chloro-aniline With hydrogenchloride; sodium nitrite In ethyl acetate at 0℃; for 0.5h;
Stage #2: With sodium azide In ethyl acetate at 20℃; for 2h;
91%
Stage #1: 3-chloro-aniline With hydrogenchloride In water; ethyl acetate at 0℃; for 0.166667h;
Stage #2: With sodium nitrite In water; ethyl acetate for 0.5h;
Stage #3: With sodium azide In water; ethyl acetate for 0.5h;
88%
2-Bromoacetyl bromide
598-21-0

2-Bromoacetyl bromide

3-chloro-aniline
108-42-9

3-chloro-aniline

2-bromo-N-(3-chlorophenyl)acetamide
41964-65-2

2-bromo-N-(3-chlorophenyl)acetamide

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0℃; for 1.25h; Inert atmosphere;100%
With triethylamine In dichloromethane at 0℃; for 1.25h; Inert atmosphere;100%
With triethylamine at 0℃; for 1h; Inert atmosphere;100%
3-chloro-aniline
108-42-9

3-chloro-aniline

trifluoroacetic anhydride
407-25-0

trifluoroacetic anhydride

N-(3-chlorophenyl)-2,2,2-trifluoro-acetamide
40410-54-6

N-(3-chlorophenyl)-2,2,2-trifluoro-acetamide

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran at 0 - 20℃; for 0.75h;100%
With triethylamine In dichloromethane at 0 - 25℃; for 12h; Inert atmosphere;91%
With triethylamine In dichloromethane at -78 - 26℃; for 1h;2.29 g
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

N-tert-butyloxycarbonylpiperidin-4-one
79099-07-3

N-tert-butyloxycarbonylpiperidin-4-one

3-chloro-aniline
108-42-9

3-chloro-aniline

tert-butyl-4-(3-chlorophenylamino)-4-cyanopiperidine-1-carboxylate

tert-butyl-4-(3-chlorophenylamino)-4-cyanopiperidine-1-carboxylate

Conditions
ConditionsYield
In acetic acid at 0℃;100%
In acetic acid at 0 - 20℃;
3-chloro-aniline
108-42-9

3-chloro-aniline

2-chloro-5-methoxyquinoline
160893-07-2

2-chloro-5-methoxyquinoline

N-(3-chlorophenyl)-5-methoxyquinolin-2-amine

N-(3-chlorophenyl)-5-methoxyquinolin-2-amine

Conditions
ConditionsYield
In neat (no solvent) at 160℃;100%
In neat (no solvent) at 160℃;
1,3-Dimethyladamantane-5-carboxylic acid chloride
3124-87-6

1,3-Dimethyladamantane-5-carboxylic acid chloride

3-chloro-aniline
108-42-9

3-chloro-aniline

N-(3-chlorophenyl)-3,5-dimethyladamantane-1-carboxamide

N-(3-chlorophenyl)-3,5-dimethyladamantane-1-carboxamide

Conditions
ConditionsYield
With triethylamine In acetone at 90℃; for 3h; Inert atmosphere;100%
3-chloro-aniline
108-42-9

3-chloro-aniline

2,4,6-tribromo-3-chloroaniline
89284-57-1

2,4,6-tribromo-3-chloroaniline

Conditions
ConditionsYield
With hydrogenchloride; dihydrogen peroxide; sodium bromide In water at 15℃; for 2h;99.8%
With bromine In tetrachloromethane at 20 - 40℃;91%
With methanol; P-benzyltriphenylphosphonium tribromide; sodium hydrogencarbonate In dichloromethane for 0.166667h; Ambient temperature;86%
Camphorsulfonyl chloride
21286-54-4

Camphorsulfonyl chloride

3-chloro-aniline
108-42-9

3-chloro-aniline

(1S)-2-oxo-bornane-10-sulfonic acid-(3-chloro-anilide)
132886-02-3, 132957-82-5

(1S)-2-oxo-bornane-10-sulfonic acid-(3-chloro-anilide)

Conditions
ConditionsYield
With dmap In acetonitrile at 0℃; for 1h; Inert atmosphere;99%
3-chloro-aniline
108-42-9

3-chloro-aniline

3-chloro-4-iodoaniline
135050-44-1

3-chloro-4-iodoaniline

Conditions
ConditionsYield
With sodium hydrogencarbonate; N,N,N-trimethylbenzenemethanaminium dichloroiodate In methanol; dichloromethane at 20℃; for 0.416667h;99%
With tetramethylammonium dibromoiodate(I) at 20℃; for 0.116667h;97%
With iodine at 30℃; for 12h; Green chemistry;95%
3-chloro-aniline
108-42-9

3-chloro-aniline

aniline
62-53-3

aniline

Conditions
ConditionsYield
With hydrogen; triethylamine In water at 120 - 140℃; under 22502.3 - 37503.8 Torr;99%
With lithium at 230℃; Zersetzen der Reaktionsprodukte mit Wasser;
With potassium fluoride; polymethylhydrosiloxane; palladium diacetate In tetrahydrofuran at 20℃; for 0.75h;94 % Spectr.
3-chloro-aniline
108-42-9

3-chloro-aniline

acryloyl chloride
814-68-6

acryloyl chloride

N-(3-chlorophenyl)acrylamide
7017-16-5

N-(3-chlorophenyl)acrylamide

Conditions
ConditionsYield
With potassium carbonate In water; acetone at 20℃;99%
With ammonia; N,N-dimethyl-aniline In benzene
3-chloro-aniline
108-42-9

3-chloro-aniline

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

N-(3-chlorophenyl)anthranilic acid
13278-36-9

N-(3-chlorophenyl)anthranilic acid

Conditions
ConditionsYield
With copper(I) oxide; copper; potassium carbonate In 2-ethoxy-ethanol at 130℃; for 24h;99%
With pyridine; copper; potassium carbonate In water for 1h; Heating;60%
With copper; potassium carbonate for 5h; Heating;44%
3-chloro-aniline
108-42-9

3-chloro-aniline

1-methyl-d3-1H-indole-2,3-dione

1-methyl-d3-1H-indole-2,3-dione

C15H8(2)H3ClN2O

C15H8(2)H3ClN2O

Conditions
ConditionsYield
In toluene Heating;99%
3-chloro-aniline
108-42-9

3-chloro-aniline

3-chlorobenzenediazonium tetrafluoroborate
456-39-3

3-chlorobenzenediazonium tetrafluoroborate

Conditions
ConditionsYield
Stage #1: 3-chloro-aniline With boron trifluoride diethyl etherate In acetonitrile Cooling with ice;
Stage #2: With isopentyl nitrite In acetonitrile at 0℃; for 0.5h;
99%
With tetrafluoroboric acid; sodium nitrite In water Diazotization;95%
Stage #1: 3-chloro-aniline With hydrogenchloride; sodium nitrite In water for 0.166667h; Cooling with ice;
Stage #2: With sodium tetrafluoroborate for 0.5h; Cooling with ice;
74%
6-chlorouracil
4270-27-3

6-chlorouracil

3-chloro-aniline
108-42-9

3-chloro-aniline

6-(3-chlorophenylamino)pyrimidine-2,4(1H,3H)-dione
7269-03-6

6-(3-chlorophenylamino)pyrimidine-2,4(1H,3H)-dione

Conditions
ConditionsYield
at 170℃; for 0.333333h;99%
for 2h; Reflux;95%
In melt at 180 - 200℃;

108-42-9Related news

Excess molar volumes, speeds of sound and viscosities for binary mixtures of 3-Chloroaniline (cas 108-42-9) with selected di- and tri-chloro substituted benzene at various temperatures: Comparison with Prigogine–Flory–Patterson theory08/26/2019

Excess volume (VE), excess isentropic compressibility (κsE), viscosity deviation (8η) and excess Gibbs energy of activation of viscous flow (G*E) for binary mixtures of 3-chloroaniline (CA) with 1,2-dichlorobenzene (1,2-DCB), 1,3-dichlorobenzene (1,3-DCB) and 1,2,4-trichlorobenzene (1,2,4-TCB)...detailed

Ultrasonic and photochemical degradation of chlorpropham and 3-Chloroaniline (cas 108-42-9) in aqueous solution08/25/2019

Sonolysis and photolysis are compared for the transformation of chlorpropham, a systemic herbicide belonging to the carbamate group, and 3-chloroaniline, the main intermediate often observed in the degradation of chlorpropham. In both cases the ultrasonic degradation is much more efficient at 48...detailed

Dielectric relaxation study of 2 and 3-Chloroaniline (cas 108-42-9) and 2 and 3-methoxyaniline with 1,4-dioxane mixtures using time domain technique08/23/2019

The dielectric relaxation measurements in the frequency range of 10 MHz to 30 GHz have been carried out for 2-chloroaniline, 3-chloroaniline, 2-methoxyaniline and 3-methoxyaniline with 1,4-dioxane mixtures over the entire concentration at 25 °C using a picosecond time domain reflectometry techn...detailed

Molecular interactions and theoretical estimation of ultrasonic speeds using scaled particle theory in binary mixtures of 3-Chloroaniline (cas 108-42-9) and 1-alkanols (C6–C10) at different temperatures08/22/2019

Density (ρ), speed of sound (u) and viscosity (η) have been measured for the binary mixtures of 3-chloroaniline with 1-alkanols (1-hexanol, 1-heptanol, 1-octanol, 1-decanol) over the entire composition range at (303.15, 308.15, 313.15, and 318.15) K. By using this data, the excess volume (VE),...detailed

Volumetric, acoustic and spectroscopic properties of 3-Chloroaniline (cas 108-42-9) with substituted ethanols at various temperatures08/21/2019

Densities (ρ), speeds of sound (u) and viscosities (η) have been measured for the binary mixtures containing 3-chloroaniline with substituted ethanol such as 2-phenylethanol, 2-chloroethanol and 2-aminoethanol at T = (303.15 to 318.15) K. These experimental data have been used to calculate exc...detailed

Studies of physical properties on molecular interactions in binary liquid mixtures of 3-Chloroaniline (cas 108-42-9) with isomeric butanols at different temperatures08/20/2019

The thermophysical parameters, viz. excess molar volume (VE), viscosity (η), speed of sound (u) and spectroscopic parameter (FTIR) have been measured for binary mixtures of 3-chloroaniline with isomeric butanols (1-butanol, 2-butanol and 2-methyl-2-propanol) over the entire range of mole fracti...detailed

Thermodynamic properties of binary liquid systems of ethanoic acid, propanoic acid, and butanoic acid with 3-Chloroaniline (cas 108-42-9) as a function of various temperatures08/19/2019

The densities (ρ) and viscosities (η) are reported for binary mixtures of 3-chloroaniline with carboxylic acids such as ethanoic acid, propionic acid and butanoic acid over the entire range of mole fractions at T = (303.15–318.15) K and at constant atmospheric pressure. The excess properties ...detailed

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