148043-61-2Relevant academic research and scientific papers
NEIGHBORING SULFUR PARTICIPATION IN THE SOLVOLYSIS OF 2-(ω-ALKYLTHIOALKYL)-3-METHYL-2-CYCLOHEXENYL p-NITROBENZOATES
Ladika, Mladen,Jursic, Branko,Mihalic, Zlatko,Sunko, Dionis E.
, p. 1703 - 1706 (1986)
As shown by kinetic and product analysis, the solvolysis of 7 and 8 in 97percent TFE includes several competitive reactions, one of them being neighboring sulfur participation and formation of intermediate cyclic sulfonium cation.
