148162-11-2Relevant academic research and scientific papers
Dinitrogen and Related Compounds of Molybdenum with the Tripodal Phosphines N(CH2CH2PPh2)3 or P(CH2CH2PPh2)3 as Coligands
Fernandez-Trujillo, Maria J.,Basallote, Manuel G.,Valerga, Pedro,Puerta, Maria C.
, p. 923 - 926 (1993)
The reduction of with a sodium dispersion in tetrahydrofuran (thf) under a dinitrogen atmosphere yields the unstable complex cis-, which decomposes in a few days even in solution under dinitrogen.Studies of the chemical reactivity of this compound towards carbon monoxide, PMe3, MeI and CF3CO2H have been carried out and the complexes , , and have been isolated and identified.The reduction of the analogous complex gives unstable trans-.The ligand-substitution reaction of cis- with N(CH2CH2PPh2)3 yields the complex cis-.
