Dinitrogen and Related Compounds of Molybdenum with the Tripodal Phosphines N(CH2CH2PPh2)3 or P(CH2CH2PPh2)3 as Coligands

DOI: 10.1039/DT9930000923

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 923 - 926 (1993)

Update date:2022-08-03

Topics:

Authors:

Fernandez-Trujillo, Maria J.

Basallote, Manuel G.

Valerga, Pedro

Puerta, Maria C.

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Article abstract of DOI:10.1039/DT9930000923

The reduction of with a sodium dispersion in tetrahydrofuran (thf) under a dinitrogen atmosphere yields the unstable complex cis-, which decomposes in a few days even in solution under dinitrogen.Studies of the chemical reactivity of this compound towards carbon monoxide, PMe3, MeI and CF3CO2H have been carried out and the complexes , , and have been isolated and identified.The reduction of the analogous complex gives unstable trans-.The ligand-substitution reaction of cis- with N(CH2CH2PPh2)3 yields the complex cis-.

Full text of DOI:10.1039/DT9930000923

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