148312-04-3Relevant academic research and scientific papers
Synthesis of 1-(triphenylsilyl)cyclopropene Derivatives, Involving Regioselective β-Addition of Sulphonyl Anions to an α,β-Epoxysilane
Jankowski, P.,Wicha, J.
, p. 2217 - 2228 (2007/10/02)
Anions generated from primary alkyl phenyl sulphones (2a-g) react with triphenylsilyloxirane (1b) to yield products of addition in the β-position (3a-g).Adducts 3a-3e were transformed into the corresponding cyclopropane derivatives (5a-5e) via mesylates (4a-4e).Representative cyclopropanes 5a-5c on treatment with n-butyllithium afford cyclopropene derivatives (6a-6c). cyclopropene, cyclopropane, (α,β-epoxyalkyl)silanes
Regioselective β-Addition of Sulfonyl Anions to an α,β-Epoxysilane. Use of Triphenylsilyloxirane for Synthesis of Stable Cyclopropene Derivatives
Jankowski, Pawel,Wicha, Jerzy
, p. 802 - 803 (2007/10/02)
Anions generated from primary alkyl phenyl sulfones react with triphenylsilyloxirane to yield products of addition in the β-position, which were used for synthesis of stable cyclopropene derivatives.
