148324-06-5

Upstream product

• 74152-53-7 O¹,O²-isopropylidene-O³-methanesulfonyl-α-D-xylo-5,6-dideoxy-hex-5-enofuranose 
• 81927-55-1 O-benzyl 2,2,2-trichloroacetimidate 
• 148324-13-4 6-O-benzyl-5-deoxy-1,2-O-isopropylidene-3-O-methanesulfonyl-D-glucofuranose 
• 94530-14-0 6-O-benzyl-5-deoxy-1,2-O-isopropylidene-α-D-xylo-hexofuranose 
• 94844-70-9 5-deoxy-1,2-O-isopropylidene-3-O-methanesulfonyl-D-glucofuranose 

Downstream Products

• 198706-76-2 7-O-benzyl-6-deoxy-D-xyloheptulose 

Relevant academic research and scientific papers

Chemoenzymatic carbon-carbon bond formation leading to non-carbohydrate derivative. Stereoselective synthesis of pentamycin C-11-C-16 fragment

Chemoenzymatic formation of 8 from an aldehyde 5 and dihydroxyacetone phosphate 6 was achieved by the use of fructose 1,6-diphosphate aldolase as a catalyst. Transformation of 8 to 20, corresponding to pentamycin C-11-C-16 fragment, was accomplished via 18a and 18b by chemical processes.