148409-86-3

Upstream product

• 77086-38-5 ketene t-butyldimethylsilyl methyl acetal 
• 81445-44-5 (S)-2-(benzyloxy)propanal 
• 53346-05-7 2-(benzyloxy)propanal 

Downstream Products

• 74262-67-2 methyl (3SR,4RS)-4-(benzyloxy)-3-hydroxypentanoate 
• 335022-98-5 1-[(2S,3R)-2-benzyloxy-5-(2-naphthyloxy)-3-pentyl]imidazole-4-carboxamide 
• 294862-80-9 1-[(2S,3R)-2-benzyloxy-5-(tert-butyldimethylsilyloxy)-3-pentyl]imidazole-4-carboxamide 
• 294863-25-5 1-[(2S,3R)-2-benzyloxy-5-methylsulfonyloxy-3-pentyl]imidazole-4-carboxamide 
• 294863-24-4 1-[(2S,3R)-2-benzyloxy-5-hydroxy-3-pentyl]imidazole-4-carboxamide 
• 700363-47-9 (3S,4S)-4-benzyloxy-1-(tert-butyldimethylsilyloxy)pentan-3-ol 
• 294862-91-2 (3S,4S)-4-benzyloxypentane-1,3-diol 

Relevant academic research and scientific papers

A Rapid Injection NMR Study of the Chelation Controlled Mukaiyama Aldol Addition: TiCl4 Versus LiClO4 as the Lewis Acid

The concept of chelation controlled addition to chiral alkoxy aldehydes using Lewis acids and mild C-nucleophiles has been extended to include cyclopropylation.The mechanism of the TiCl4-mediated chelation controlled addition of enolsilanes and allylsilan

Carbon-carbon bond formation catalyzed by lithium perchlorate in dichloromethane

A catalytic amount of lithium perchlorate suspended in dichloromethane provides a mild and effective medium for Mukaiyama aldol reactions of aldehydes with silyl ketene acetal (1). 2-Cyclohexenone undergoes clean 1,4-addition under similar conditions. Catalyst activity is much higher in dichloromethane than in diethyl ether.