148409-86-3Relevant articles and documents
A Rapid Injection NMR Study of the Chelation Controlled Mukaiyama Aldol Addition: TiCl4 Versus LiClO4 as the Lewis Acid
Reetz, Manfred T.,Raguse, Burkhard,Marth, Charles F.,Huegel, Helmut M.,Bach, Thorsten,Fox, David N. A.
, p. 5731 - 5742 (1992)
The concept of chelation controlled addition to chiral alkoxy aldehydes using Lewis acids and mild C-nucleophiles has been extended to include cyclopropylation.The mechanism of the TiCl4-mediated chelation controlled addition of enolsilanes and allylsilan