14846-50-5Relevant academic research and scientific papers
Catalytic Reductive Cleavage of Poly(phenylene sulfide) Using a Hydrosilane
Minami, Yasunori,Matsuyama, Nao,Matsuo, Yasuaki,Tamura, Masanori,Sato, Kazuhiko,Nakajima, Yumiko
supporting information, p. 3351 - 3354 (2021/07/17)
The solvent-insoluble poly(phenylene sulfide) main chain was reductively cleaved by using triethylsilane as a hydrogen source under palladium/I c Hex catalytic conditions. After the reaction, benzene and bis(triethylsilyl) sulfide as a sulfide source were formed efficiently. This method could be operated on a gram scale.
Desulfurization and H-migration of secondary thioamides catalyzed by an iron complex to yield imines and their reaction mechanism
Fukumoto, Kozo,Sakai, Akane,Hayasaka, Kazumasa,Nakazawa, Hiroshi
supporting information, p. 2889 - 2892 (2013/06/27)
Secondary thioamides were converted into imines as the major products using hydrosilane in the presence of an iron catalyst. An iron carbene complex with a silyl thiolato ligand was isolated as one of the intermediates of the catalytic cycle and was characterized by X-ray analysis.
REACTIONS OF TRIORGANOSILYLSULFENYL HALIDES WITH SOME NUCLEOPHILES
Kowalski, J.,Chojnowski, J.,Michalski, J.
, p. 1 - 6 (2007/10/02)
The reaction of triorganosilylsulfenyl halides R3SiSX (R=Ph, Et; X=Cl, Br) with carbon-carbon double bonds, trialkyl phosphites, and organometallic reagents have been studied.With the first two nucleophiles the course of the reactions differed from that with organosulfenyl chlorides because of nucleophilic attack of halide ion on silyl group.
