14846-50-5Relevant articles and documents
Catalytic Reductive Cleavage of Poly(phenylene sulfide) Using a Hydrosilane
Minami, Yasunori,Matsuyama, Nao,Matsuo, Yasuaki,Tamura, Masanori,Sato, Kazuhiko,Nakajima, Yumiko
supporting information, p. 3351 - 3354 (2021/07/17)
The solvent-insoluble poly(phenylene sulfide) main chain was reductively cleaved by using triethylsilane as a hydrogen source under palladium/I c Hex catalytic conditions. After the reaction, benzene and bis(triethylsilyl) sulfide as a sulfide source were formed efficiently. This method could be operated on a gram scale.
REACTIONS OF TRIORGANOSILYLSULFENYL HALIDES WITH SOME NUCLEOPHILES
Kowalski, J.,Chojnowski, J.,Michalski, J.
, p. 1 - 6 (2007/10/02)
The reaction of triorganosilylsulfenyl halides R3SiSX (R=Ph, Et; X=Cl, Br) with carbon-carbon double bonds, trialkyl phosphites, and organometallic reagents have been studied.With the first two nucleophiles the course of the reactions differed from that with organosulfenyl chlorides because of nucleophilic attack of halide ion on silyl group.
