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994-49-0

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994-49-0 Usage

Uses

Hexaethyldisiloxane is used as a pharmaceutical intermediate.

Check Digit Verification of cas no

The CAS Registry Mumber 994-49-0 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 9,9 and 4 respectively; the second part has 2 digits, 4 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 994-49:
(5*9)+(4*9)+(3*4)+(2*4)+(1*9)=110
110 % 10 = 0
So 994-49-0 is a valid CAS Registry Number.
InChI:InChI=1/C12H30OSi2/c1-7-14(8-2,9-3)13-15(10-4,11-5)12-6/h7-12H2,1-6H3

994-49-0 Well-known Company Product Price

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  • Alfa Aesar

  • (L04367)  Hexaethyldisiloxane, 99%   

  • 994-49-0

  • 5g

  • 735.0CNY

  • Detail

994-49-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name Hexaethyldisiloxane

1.2 Other means of identification

Product number -
Other names triethyl(triethylsilyloxy)silane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:994-49-0 SDS

994-49-0Relevant academic research and scientific papers

Ga+-catalyzed hydrosilylation? about the surprising system Ga+/HSiR3/olefin, proof of oxidation with subvalent Ga+and silylium catalysis with perfluoroalkoxyaluminate anions

Barthélemy, Antoine,Glootz, Kim,Hanske, Annaleah,Krossing, Ingo,Scherer, Harald

, p. 439 - 453 (2022/01/22)

Already 1 mol% of subvalent [Ga(PhF)2]+[pf]- ([pf]- = [Al(ORF)4]-, RF = C(CF3)3) initiates the hydrosilylation of olefinic double bonds under mild conditions. Reactions with HSiMe3 and HSiEt3 as substrates efficiently yield anti-Markovnikov and anti-addit

A New Protocol for Catalytic Reduction of Alkyl Chlorides Using an Iridium/Bis(benzimidazol-2′-yl)pyridine Catalyst and Triethylsilane

Fukuyama, Takahide,Hamada, Yuki,Ryu, Ilhyong

supporting information, p. 3404 - 3408 (2021/07/14)

The reduction of alkyl chlorides using triethylsilane is investigated. Primary, secondary, tertiary, and benzylic C-Cl bonds are effectively converted into C-H bonds using an [IrCl(cod)] 2/2,6-bis(benzimidazol-2′-yl)pyridine catalyst system. This catalyst system is quite simple since the tridentate N-ligand can be easily prepared in one step from commercially available reagents.

Reversible Silylium Transfer between P-H and Si-H Donors

Belli, Roman G.,Pantazis, Dimitrios A.,McDonald, Robert,Rosenberg, Lisa

supporting information, p. 2379 - 2384 (2020/12/07)

The Mo=PR2 π* orbital in a Mo phosphenium complex acts as acceptor in a new PIII-based Lewis superacid. This Lewis acid (LA) participates in electrophilic Si-H abstraction from E3SiH to give a Mo-bound secondary phosphine ligand, Mo-PR2H. The resulting Et3Si+ ion remains associated with the Mo complex, stabilized by η1-P-H donation, yet undergoes rapid exchange with an η1-Si-H adduct of free silane in solution. The equilibrium between these two adducts presents an opportunity to assess the role of this new LA in catalytic reactions of silanes: is the LA acting as a catalyst or as an initiator? Preliminary results suggest that a cycle including the Mo-bound phosphine-silylium adduct dominates in the catalytic hydrosilylation of acetophenone, relative to a putative cycle involving the silane-silylium adduct or “free” silylium.

Rapid Broad Spectrum Detection of Carbapenemases with a Dual Fluorogenic-Colorimetric Probe

Ma, Chi-Wang,Ng, Kenneth King-Hei,Yam, Bill Hin-Cheung,Ho, Pak-Leung,Kao, Richard Yi-Tsun,Yang, Dan

supporting information, p. 6886 - 6894 (2021/05/29)

Carbapenems stand as one of the last-resort antibiotics; however, their efficacy is threatened by the rising number and rapid spread of carbapenemases. Effective antimicrobial stewardship thus calls for rapid tests for these enzymes to aid appropriate prescription and infection control. Herein, we report the first effective pan-carbapenemase reporter CARBA-H with a broad scope covering all three Ambler classes. Using a chemical biology approach, we demonstrated that the absence of the 1β-substituent in the carbapenem core is key to pan-carbapenemase recognition, which led to our rational design and probe development. CARBA-H provides a dual colorimetric-fluorogenic response upon carbapenemase-mediated hydrolysis. A clear visual readout can be obtained within 15 min when tested against a panel of carbapenemase-producing Enterobacteriaceae (CPE) clinical isolates that notably includes OXA-48 and OXA-181-producing strains. Furthermore, CARBA-H can be applied to the detection of carbapemenase activity in CPE-spiked urine samples.

Catalytic CO2 hydrosilylation with [Mn(CO)5Br] under mild reaction conditions

García, Juventino J.,González, Tania

supporting information, (2021/06/07)

Carbon dioxide hydrosilylation with earth-abundant transition-metal catalysts is an attractive alternative for the design of greener and cost-effective synthetic strategies. Herein, simple [Mn(CO)5Br] is an efficient precatalyst in the hydrosilylation of carbon dioxide with Et3SiH under mild reaction conditions. Using THF as a solvent, triethylsilylformate Et3SiCH(O)O was obtained in 67% yield after 1 h at 50 °C and 4 bar of CO2 pressure. The selectivity of the reaction was tuned by changing the solvent to a mixture of THF and toluene producing bis(triethylsilyl)acetal (Et3SiO)2CH2 in 86% yield. The CO2 hydrosilylation was also effective at room temperature and atmospheric pressure using either THF or the mixture THF/toluene as the solvent resulting in high Et3SiH conversion (92%–99%) but with a decrease in the selectivity. Radical trapping experiments indicated the participation of radical species in the catalytic mechanism. To the best of our knowledge, this is the first report on CO2 hydrosilylation catalyzed by transition-metal radical intermediates.

Oxidation of Triorganosilanes and Related Compounds by Chlorine Dioxide

Grabovskiy, S. A.,Kabal’nova, N. N.

, p. 2391 - 2402 (2022/01/22)

Abstract: Oxidation of triethylsilane, tert-butyldimethylsilane, dimethylphenylsilane, triphenylsilane, 1,1,1,2tetramethyl-2-phenyldisilane, tris(trimethylsilyl)silane, hexamethyldisilane, tetrakis(trimethylsilyl)silane, 1,1,3,3tetraisopropyldisiloxane with chlorine dioxide was carried out. The reaction products of studied triorganosilanes with chlorine dioxide in an acetonitrile solution were the corresponding silanols and siloxanes. A mechanism explaining the formation of products and the observed regularities of the oxidation of silanes with chlorine dioxide has been proposed. A thermochemical analysis of some possible pathways in the gas phase using methods G4, G3, M05, and in an acetonitrile solution by the SMD-M05 method was carried out. The oxidation process can occur both with the participation of ionic and radical intermediates, depending on the structure of the oxidized substrate and medium.

Hydrosilylative reduction of carbon dioxide by a homoleptic lanthanum aryloxide catalyst with high activity and selectivity

Chang, Kejian,Maron, Laurent,Xu, Xin,Zheng, Xizhou,del Rosal, Iker

supporting information, p. 7804 - 7809 (2021/06/16)

An efficient tandem hydrosilylation of CO2, which uses a combination of a simple, homoleptic lanthanum aryloxide and B(C6F5)3, was performed. Use of a less sterically hindered silane led to an exclusive reduction of CO2to CH4, with a turnover frequency of up to 6000 h?1at room temperature. The catalytic system is robust, and 19?400 turnovers could be achieved with 0.005 mol% loading of lanthanum. The reaction outcome depended highly on the nature of the silane reductant used. Selective production of the formaldehyde equivalent,i.e., bis(silyl)acetal, without over-reduction, was observed when a sterically bulky silane was used. The reaction mechanism was elucidated by stoichiometric reactions and DFT calculations.

Chemoselective Hydrosilylation of the α,β-Site Double Bond in α,β- And α,β,γ,δ-Unsaturated Ketones Catalyzed by Macrosteric Borane Promoted by Hexafluoro-2-propanol

Zhan, Xiao-Yu,Zhang, Hua,Dong, Yu,Yang, Jian,He, Shuai,Shi, Zhi-Chuan,Tang, Lei,Wang, Ji-Yu

, p. 6578 - 6592 (2020/07/17)

The B(C6F5)3-catalyzed chemoselective hydrosilylation of α,β- and α,β,γ,δ-unsaturated ketones into the corresponding non-symmetric ketones in mild reaction conditions is developed. Nearly 55 substrates including those bearing reducible functional groups such as alkynyl, alkenyl, cyano, and aromatic heterocycles are chemoselectively hydrosilylated in good to excellent yields. Isotope-labeling studies revealed that hexafluoro-2-propanol also served as a hydrogen source in the process.

Silylation of Alcohols, Phenols, and Silanols with Alkynylsilanes – an Efficient Route to Silyl Ethers and Unsymmetrical Siloxanes

Kuciński, Krzysztof,Stachowiak, Hanna,Hreczycho, Grzegorz

, p. 4042 - 4049 (2020/07/04)

The formation of several silyl ethers (alkoxysilanes, R3Si-OR') and unsymmetrical siloxanes (R3Si-O-SiR'3) can be catalyzed by the commercially available potassium bis(trimethylsilyl)amide (KHMDS). The reaction proceeds via direct dealkynative coupling between various alcohols or silanols and alkynylsilanes, with a simultaneous formation of gaseous acetylene as the sole by-product. The dehydrogenative and dealkenative coupling of alcohols or silanols are well-investigated, whilst the utilization of alkynylsilanes as silylating agents has never been comprehensively studied in this context. Overall, the presented system allows the synthesis of various attractive organosilicon compounds under mild conditions, making this approach an atom-efficient, environmentally benign, and sustainable alternative to existing synthetic solutions.

Catalytic Disproportionation of Formic Acid to Methanol by using Recyclable Silylformates

Cantat, Thibault,Chauvier, Clément,Imberdis, Arnaud,Thuéry, Pierre

supporting information, p. 14019 - 14023 (2020/06/09)

A novel strategy to prepare methanol from formic acid without an external reductant is presented. The overall process described herein consists of the disproportionation of silyl formates to methoxysilanes, catalyzed by ruthenium complexes, and the production of methanol by simple hydrolysis. Aqueous solutions of MeOH (>1 mL, >70 percent yield) were prepared in this manner. The sustainability of the reaction has been established by recycling of the silicon-containing by-products with inexpensive, readily available, and environmentally benign reagents.

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