148587-27-3Relevant academic research and scientific papers
Application of ene-like reactions of aldehydes with vinyl ethers: Facile assembly of benzazocenone intermediates for mitomycinoids
Ciufolini, Marco A.,Chen, Mingying,Lovett, Dennis P.,Deaton, Melissa V.
, p. 4355 - 4358 (1997)
Benzazocenone intermediates for mitomycinoids are now available in only sin steps. Key phases of this sequence include the ene-like reaction of 2-methoxypropene with a 2-azidophenylacetaldehyde and a novel heterocyclic ring formation/expansion reaction.
A remarkable ene-like reaction: Development and synthetic applications
Ciufolini, Marco A.,Deaton, Melissa V.,Zhu, Shuren,Chen, Mingying
, p. 16299 - 16312 (2007/10/03)
A catalytic ene-like reaction of aldehydes with those vinyl ethers that display the oxygen functionality at the central carbon of an allylic system, e.g., 2-methoxypropene, is discussed in detail. The reaction is promoted by 0.05 equiv. of the 1:1 complex
Yb(fod)3-promoted ene reaction of aldehydes with vinyl ethers
Deaton, Melissa V.,Ciufolini, Marco A.
, p. 2409 - 2412 (2007/10/02)
Catalytic amounts of Yb(fod)3 catalyze a bimolecular ene-like reaction between ordinary aldehydes and vinyl ethers, in which the oxygen functionality is located at the central carbon of an allylic system. These reactions proceed at room tempera
