14877-90-8

Basic information

• Product Name: Rhodium, carbonylchlorobis(triphenylarsine)-
• CAS NO: 14877-90-8
• Molecular Formula: C37H30As2ClORh
• Molecular Weight: 778.846
• Mol File: 14877-90-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Rhodium, carbonylchlorobis(triphenylarsine)-(CAS DataBase Reference)
• NIST Chemistry Reference: Rhodium, carbonylchlorobis(triphenylarsine)-(14877-90-8)
• EPA Substance Registry System: Rhodium, carbonylchlorobis(triphenylarsine)-(14877-90-8)

Safety Data

• Hazardous Substances Data: 14877-90-8(Hazardous Substances Data)

Upstream product

• 603-32-7 triphenyl-arsane 
• 14973-92-3 RhCl(AsPh₃)3 

Downstream Products

• 116466-23-0 trans-Rh(AsPh₃)2(CO)(triflate) 
• 72859-59-7 RhBr₃(As(C₆H₅)3)2 
• 64537-32-2 Rh(CO)(NO)ClBr(As(C₆H₅)3)2 
• 77535-69-4 Rh(CO)(NO)Cl₂(As(C₆H₅)3)2 
• 74428-07-2 Rh(CO)Cl(As(C₆H₅)3)2(SAs(C₆H₅)3) 
• 111143-58-9 carbonyl(bis(2-(diphenylphosphino)ethyl)benzylamine)rhodium(I)chloride 
• 75215-13-3 Rh(CO)(As(C₆H₅)3)2(CH₃COCH₃)⁽¹⁺⁾*ClO₄^(1-)=[Rh(CO)(As(C₆H₅)3)2(CH₃COCH₃)][ClO₄] 
• 111143-59-0 carbonyl(bis(2-(diphenylarsino)ethyl)benzylamine)rhodium(I)chloride 
• 100908-49-4 C₆H₅CH₂CH₂C₂Pt(P(C₆H₅)2CH₂P(C₆H₅)2)2C₂C₆H₅CH₂CH₂RhCO⁽¹⁺⁾*Cl^(1-)=(C₂C₆H₅CH₂CH₂)Pt(P(C₆H₅)2CH₂P(C₆H₅)2)2C₂C₆H₅CH₂CH₂RhCOCl 
• 15694-93-6 {(C₆H₅)3As}2Rh(CO)ClBBr₃ 
• 172991-38-7 Rh₂Cl₂C₆H₄[CH₂N(CH₂CH₂P(C₆H₅)2)2]2(CO)2 

Relevant articles and documents

α-cationic arsines: Synthesis, structure, reactivity, and applications

A series of structurally differentiated cationic arsines containing imidazolium, cyclopropenium, formamidinium, and pyridinium substituents have been synthesized through short and scalable routes. Evaluation of the donor properties of these compounds by IR spectroscopy and DFT calculations reveals similar σ-electron-releasing abilities for all of them; however, their π-acceptor properties are strongly influenced by the nature of the positively charged group. We describe the coordination chemistry of the newly prepared α-cationic arsines toward different metal centers and their reactivity in the presence of strong oxidants to afford cationic As(V) species. Their unique electronic properties have been exploited in Pt(II) catalysis to develop a new catalyst with remarkable activity in the cycloisomerization of enynes to trisubstituted cyclopropanes. To the best of our knowledge, this is the first report on the use of α-cationic arsine ligands in catalysis.