72859-59-7Relevant academic research and scientific papers
Rhodium Nitrosyl Complexes
Pandey, K. K.,Agarwala, U. C.
, p. 673 - 676 (2007/10/02)
The reactions of nitrosyl chloride and nitrosyl bromide with rhodium(I) complexes containing triphenylphosphine and triphenylarsine have been studied.These reactions result in the formation of the complexes of the type (X = Cl, Br; L = PPh3, AsPh3) and Rh(NO)X3L2.Reactions of Rh(CO)(NO)ClX(PPh3)2 (X = Cl, Br) with hydrazine hydrate afford PhH(CO)(PPh3)3 and a highly hygroscopic red complex X (X = Cl or Br).The probable structures of these complexes have been proposed on the basis of elemental analyses, spectroscopic (IR, UV and EPR) and magnetic data.
