148917-41-3

Basic information

• Product Name: Acetic acid (3aR,4S,6R,6aS)-2,2-dimethyl-6-phenoxy-tetrahydro-cyclopenta[1,3]dioxol-4-yl ester
• Synonyms: Acetic acid (3aR,4S,6R,6aS)-2,2-dimethyl-6-phenoxy-tetrahydro-cyclopenta[1,3]dioxol-4-yl ester
• CAS NO: 148917-41-3
• Molecular Weight: 292.332
• Mol File: 148917-41-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Acetic acid (3aR,4S,6R,6aS)-2,2-dimethyl-6-phenoxy-tetrahydro-cyclopenta[1,3]dioxol-4-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid (3aR,4S,6R,6aS)-2,2-dimethyl-6-phenoxy-tetrahydro-cyclopenta[1,3]dioxol-4-yl ester(148917-41-3)
• EPA Substance Registry System: Acetic acid (3aR,4S,6R,6aS)-2,2-dimethyl-6-phenoxy-tetrahydro-cyclopenta[1,3]dioxol-4-yl ester(148917-41-3)

Safety Data

• Hazardous Substances Data: 148917-41-3(Hazardous Substances Data)

Upstream product

• 108-95-2 phenol 
• 77-76-9 2,2-dimethoxy-propane 
• 148969-52-2 (-)-(1S,4R)-4-phenyloxy-2-cyclopenten-1-yl acetate 
• 7129-41-1 6-oxabicyclo[3.1.0]hex-2-ene 
• 103056-56-0 (+/-)-cis-4-phenyloxy-2-cyclopenten-1-ol 

Downstream Products

• 104010-72-2 (3aS,6aS)-2,2-dimethyl-3a,6a-dihydro-4H-cyclopenta[d][1,3]dioxol-4-one 

Relevant articles and documents

Chemoenzymatic synthesis of a versatile cyclopentenone: (+)-(3aS,6aS)-2,2-dimethyl-3aβ,6aβ-dihydro-4H-cyclopenta-1,3-dioxol- 4-one

The title cyclopentenone has been prepared by enzymatic resolution of cis-4-phenyloxy- and cis-4-(4-methoxyphenyloxy)-cyclopent-2-en-1-ol in isopropenyl acetate using Pseudomonas cepacia lipase. The use of a 4-methoxyphenyloxy-alcohol intermediate enabled the use of both enzymatically resolved enantiomers in the synthesis of the desired (+)-enone.