148926-32-3

Upstream product

• 20672-67-7 (2S,3R,4R,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-2-methoxy-tetrahydro-pyran-3-ol 
• 1029121-53-6 benzoxazol-2-yl 2-O-benzoyl-3,4,6-tri-O-benzyl-1-thio-β-D-glucopyranoside 
• 1309666-24-7 benzimidazol-2-yl 2-O-benzoyl-3,4,6-tri-O-benzyl-1-thio-β-D-glucopyranoside 
• 40246-27-3 3,4,6-tri-O-benzyl-1,2-O-methoxybenzylidene-α-D-glucopyranose 

Relevant academic research and scientific papers

S-benzimidazolyl glycosides as a platform for oligosaccharide synthesis by an active-latent strategy

Doing the Biz: The S-benzimidazolyl (SBiz) anomeric moiety is a new leaving group that can be activated for glycosylation under a variety of conditions, including metal-assisted and alkylation pathways. Application of a substituted SBiz moiety (X=anisoyl, see picture) allows active-latent and armed-disarmed types of oligosaccharide assembly. Copyright

Superarming the S-benzoxazolyl glycosyl donors by simple 2-O-benzoyl-3,4,6-tri-O-benzyl protection

(Chemical Equation Presented) The strategic placement of common protecting groups led to the discovery of a new method for "superarming" glycosyl donors. Conceptualized from our previous studies on the O-2/O-5 Cooperative Effect, it was determined that S-