149032-75-7Relevant academic research and scientific papers
Diastereoselective Diels-Alder Reactions with α-Chloronitroso Saccharides
Braun, Heinz,Felber, Helena,Kresze, Guenter,Schmidtchen, Franz P.,Prewo, Roland,Vasella, Andrea
, p. 261 - 268 (2007/10/02)
The α-chloronitroso reagent 2 obtained from ribose via the lactone oxime 3 reacts with the dienes 6-10 at low temperature to give the chiral dihydrooxazines 11-16 in 63-96percent yield and >/=96percent enantiomeric excess.The reagents 1 and 2 which are ap
