149118-07-0

Basic information

• Product Name: (2R,3R,4R)-3,4-Bis-benzyloxy-2-benzyloxymethyl-5-phenylsulfanyl-tetrahydro-furan
• Synonyms: (2R,3R,4R)-3,4-Bis-benzyloxy-2-benzyloxymethyl-5-phenylsulfanyl-tetrahydro-furan
• CAS NO: 149118-07-0
• Molecular Weight: 512.67
• Mol File: 149118-07-0.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: (2R,3R,4R)-3,4-Bis-benzyloxy-2-benzyloxymethyl-5-phenylsulfanyl-tetrahydro-furan(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3R,4R)-3,4-Bis-benzyloxy-2-benzyloxymethyl-5-phenylsulfanyl-tetrahydro-furan(149118-07-0)
• EPA Substance Registry System: (2R,3R,4R)-3,4-Bis-benzyloxy-2-benzyloxymethyl-5-phenylsulfanyl-tetrahydro-furan(149118-07-0)

Safety Data

• Hazardous Substances Data: 149118-07-0(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 91110-24-6 Acetic acid (2S,3R,4R,5R)-3,4-bis-benzyloxy-5-benzyloxymethyl-tetrahydro-furan-2-yl ester 
• 64363-77-5 methyl 2,3,5-tri-O-benzyl-β-D-ribofuranoside 
• 14365-16-3 bis-(phenylthio)-dibutylstannane 
• 148623-62-5 2,3,5-tri-O-benzyl-1-O-methoxyacetyl-β-D-ribofuranose 
• 4551-15-9 phenylthiotrimethylsilane 
• 16838-89-4 2,3,5-tri-O-benzyl-D-ribofuranose 

Downstream Products

• 107961-04-6 α-1-deoxy-1-C-(phenylthio)-2,3,5-tri-O-benzyl-D-ribofuranose 
• 147103-50-2 1-(β-D-2',3',5'-tri-O-benzyl-ribosyl)thymine 

Relevant articles and documents

Catalytic O- and S-Glycosylation of 1-Hydroxy Sugars

O-Protected 1-hydroxy sugars are effectively cross-coupled with a variety of alcohols and thiols to give the corresponding glycosides by using methoxyacetic acid and ytterbium(III) trifluoromethanesulfonate as catalytic promoters.

A facile transformation of benzylated methyl glycosides to thioglycosides

Phenyl thioglycosides, useful glycosyl donors, were synthesized in reaction of benzylated methyl glycosides with trimethylsilylbromide and thiophenol in the presence of zinc under mild conditions.

Lanthanoid(III) triflates as new glycosylation catalysts. Selective and efficient activation of 1-O-methoxyacetyl sugars

The reactions of 1-O-methoxyacetyl sugars with alcohols or thiols were effectively promoted by a catalytic amount of lanthanoid(III) triflates such as Tb(OTf)3, Ho(OTf)3, Tm(OTf)3, and Yb(OTf)3 to give the corre