14916-43-9

Upstream product

• 1605-53-4 diethyl-phenyl-phosphine 
• 7646-79-9 cobalt(II) chloride 

Downstream Products

• 120311-63-9 Co(P(C₂H₅)2(C₆H₅))2Cl₃ 
• 94629-79-5 [Co(2,3,6-C₆H₂Cl₃)2(PEt₂Ph)2] 
• 84779-45-3 [Co(C₆H₂Cl₃)2(P(C₂H₅)2(C₆H₅))2] 
• 94607-07-5 [Co(2,3,4,6-C₆HCl₄)2(PEt₂Ph)2] 
• 30068-88-3 CoCl₂(CO)(P(C₂H₅)2C₆H₅)2 

Relevant academic research and scientific papers

Synthesis, structure and butadiene polymerization behavior of CoCl 2(PRxPh3 - X)2 (R = methyl, ethyl, propyl, allyl, isopropyl, cyclohexyl; X = 1, 2). Influence of the phosphorous ligand on polymerization stereo

Several cobalt(II) phosphine complexes have been synthesized by reacting cobalt(II) chloride with various mono- and diphenylalkylphosphines (PR xPh3 - x; R = methyl, ethyl, allyl, propyl, isopropyl, cyclohexyl; x = 1, 2). For some of

Homogeneous Isomerization of 1-Butene Catalyzed by -NaBH4 Systems (M=Co, Ni, X=Halides, SCN, PR3=PPhnEt3-n) - Acceleration by Phosphine Addition and Stereoselectivity

The stoichiometric or a little excess amount of NaBH4 was treated with (M=Co, Ni, X=halides, SCN, PR3=PPhnEt3-n) in THF-1,2-dimethoxyethane to form monohydride species which were active for isomerization of 1-butene.The reaction was accelerated by excess PPh3 in -NaBH4 systems.Other catalytic systems have optimum ratios of excess phosphine to metal for getting maximum activities.Thiocyanate-metal complexes are the most active in each Co- and Ni-catalyst system.Cis-selectivity depends on the cone angle of PR3, the size of anion ligands, and the congested structure of the complexes.