14917-13-6

Basic information

• Product Name: [tricarbonyl(triphenylphosphine)nickel]
• Synonyms: [tricarbonyl(triphenylphosphine)nickel]
• CAS NO: 14917-13-6
• Molecular Weight: 405.012
• Mol File: 14917-13-6.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: [tricarbonyl(triphenylphosphine)nickel](CAS DataBase Reference)
• NIST Chemistry Reference: [tricarbonyl(triphenylphosphine)nickel](14917-13-6)
• EPA Substance Registry System: [tricarbonyl(triphenylphosphine)nickel](14917-13-6)

Safety Data

• Hazardous Substances Data: 14917-13-6(Hazardous Substances Data)

Upstream product

• 14264-16-5 bis(triphenylphosphine)nickel(II) chloride 
• 201230-82-2 carbon monoxide 
• 27122-27-6 {N(C₄H₉-n)4}{(CO)3NiI} 
• 603-35-0 triphenylphosphine 
• 27116-04-7 {C₆H₅CH₂N(CH₃)3}⁽¹⁺⁾*{(CO)3NiCl}^(1-)={C₆H₅CH₂N(CH₃)3}{(CO)3NiCl} 
• 1295-35-8 bis(1,5-cyclooctadiene)nickel ⁽⁰⁾ 
• 84114-18-1 1-(2,4,6-tri-tert-butylphenyl)-1-phosphaethene 
• 66674-76-8 trans-P,P'-[((C₆H₅)3P)(C₆H₅)Ni(P(C₆H₅)2CHC(C₆H₅)O)] 
• 96705-44-1 Ni(CO)BrCH₂N(CH₃)2 
• 103139-72-6 tricarbonyl(2,4,6-tri-t-butylphenylmethylenephosphine)nickel⁽⁰⁾ 
• 27122-30-1 {N(C₄H₉-n)4}{(CO)3NiBr} 
• 39045-49-3 (CO)3NiCH₂P(C₆H₅)3 
• 27122-29-8 Na⁽¹⁺⁾*{(CO)3NiI}^(1-)=Na{(CO)3NiI} 
• 27116-03-6 {N(C₄H₉-n)4}{(CO)3NiCl} 

Downstream Products

• 13463-39-3 tetracarbonyl nickel 
• 13007-90-4 bis(triphenylphosphine)nickel⁽⁰⁾ dicarbonyl 

Relevant articles and documents

The infrared and Raman spectra of a triphenylphosphine derivative of Ni(CO)4

The infrared and Raman spectra of Ni(CO)3P(C6H5)3 and P(C6H5)3 in cyclohexane were obtained for the identification of the modes of vibration localized in the PNi(CO)3 group of Ni(CO)3P(C6H5)3. The Raman spectra were obtained by means of an electrodeless mercury arc powered by high-frequency radiation. The principal Raman exciting line was the 4358 ?. Hg line. The spectra are interpreted in terms of C3v symmetry for the PNi(CO)3 group and frequencies are assigned to the fundamentals. The nature of the bonding is discussed from a molecular orbital point of view and compared with that in Ni(CO)4. The C-O stretching frequencies permit one to estimate the π*CO participation index as 0.28 compared with a PI value 0.19 for a CO in Ni(CO)4. Thus, there is an increase of about 0.5 electron in the π*CO orbitals of the Ni(CO)3 moiety on passing from Ni(CO)4 to Ni(CO)3P(C6H5)3, much of which results from a substantial reduction in the charge back-transferred into the π acceptor orbitals of the P(C6H5)3 ligand from the value for CO in Ni(CO)4.

Expanding the phosphorus-carbon analogy: Formation of an unprecedented 5-phosphasemibullvalene derivative

We could access for the first time a 5-phosphasemibullvalene derivative via quantitative and selective photochemical di-π-methane rearrangement from the corresponding phosphabarrelene. Due to the striking analogy between phosphorus and carbon, this hitherto unknown transformation of vinyl-phosphorus species provides the possibility to prepare novel, chiral and conformationally rigid organophosphorus cage compounds in a straightforward manner.

Synthesis, Structure and Nickel Carbonyl Complexes of Dialkylterphenyl Phosphines

The experimental and computational characterization of a series of dialkylterphenyl phosphines, PR2Ar′ is described. The new P-donors comprise five compounds of general formula PR2ArDtpb2 (R=Me, Et, iPr, c-C5H9 and c-C6H11); ArDtpb2 = 2,6-C6H3-(3,5-C6H3-(CMe3)2)2), and another five PR2Ar′ phosphines containing the bulky alkyl groups iPr, c-C5H9 or c-C6H11, in combination with Ar′=ArXyl2, Ar Xyl'2, or Ar ph2 (L1–L10). Steric and electronic parameters have been determined computationally and from IR and X-ray data obtained for the phosphines and for some derivatives, including tricarbonyl and dicarbonyl nickel complexes, Ni(CO)3(PR2Ar′) and Ni(CO)2(PR2Ar′). In the solid state, the free phosphines PR2Ar′ adopt one of the three possible structures formally related by rotation around the Cipso?P bond. Details on their relative energies and on the influence of the free phosphine structure on its coordination chemistry towards Ni(CO)n (n = 2, 3) fragments has been obtained by experimental and computational methods.

Spectral quantum beating in mixed frequency/time-domain coherent multidimensional spectroscopy

Coherent multidimensional spectroscopy performed in the mixed frequency/time domain exhibits both temporal and spectral quantum beating when two quantum states are simultaneously excited. The excitation of both quantum states can occur because either the spectral width of the states or the excitation pulse exceeds the frequency separation of the quantum states. The quantum beating appears as a line that broadens and splits into two peaks and then recombines as the time delay between excitation pulses increases. The splitting depends on the spectral width of the excitation pulses. We observe the spectral quantum beating between the two nearly degenerate asymmetric carbonyl stretch modes in a nickel tricarbonyl chelate using the nonrephasing, ground state bleaching coherence pathway in triply vibrationally enhanced four-wave mixing as the time delay between the first two excitation pulses changes.