84114-18-1

Basic information

• Product Name: Phosphine, methylene[2,4,6-tris(1,1-dimethylethyl)phenyl]-
• CAS NO: 84114-18-1
• Molecular Formula: C19H31P
• Molecular Weight: 290.429
• Mol File: 84114-18-1.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Phosphine, methylene[2,4,6-tris(1,1-dimethylethyl)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphine, methylene[2,4,6-tris(1,1-dimethylethyl)phenyl]-(84114-18-1)
• EPA Substance Registry System: Phosphine, methylene[2,4,6-tris(1,1-dimethylethyl)phenyl]-(84114-18-1)

Safety Data

• Hazardous Substances Data: 84114-18-1(Hazardous Substances Data)

Upstream product

• 75-11-6 diiodomethane 
• 83466-54-0 Bis(2,4,6-tri-tert-butylphenyl)diphosphen 
• 103139-72-6 tricarbonyl(2,4,6-tri-t-butylphenylmethylenephosphine)nickel⁽⁰⁾ 
• 83115-12-2 (2,4,6-tri-tert-butylphenyl)phosphine 
• 177902-37-3 (E)-1-Bromo-2-(2,4,6-tri-tert-butylphenyl)-2-phosphaethenyllithium 
• 100281-23-0 [(dibromomethylene)(2,4,6-tri-tertbutylphenyl)phosphine] 
• 75-09-2 dichloromethane 
• 211817-38-8 [1-Phenylsulfanyl-meth-(Z)-ylidene]-(2,4,6-tri-tert-butyl-phenyl)-phosphane 
• 100281-31-0 (E/Z)-(Bromomethylene)(2,4,6-tri-tert-butylphenyl)phosphane 
• 186581-53-3 diazomethane 
• 211817-36-6 [1-Bromo-1-phenylsulfanyl-meth-(E)-ylidene]-(2,4,6-tri-tert-butyl-phenyl)-phosphane 
• 211817-39-9 (Bis-phenylsulfanyl-methylene)-(2,4,6-tri-tert-butyl-phenyl)-phosphane 

Downstream Products

• 103139-72-6 tricarbonyl(2,4,6-tri-t-butylphenylmethylenephosphine)nickel⁽⁰⁾ 
• 819071-24-4 H₂CP(AlCl₃)(2,4,6-tri-tert-butylphenyl) 
• 14917-13-6 [tricarbonyl(triphenylphosphine)nickel] 
• 819071-28-8 GaCl₄^(1-)*((CH₃)3C)3C₆H₂PCH₂P(N(C₂H₅)2)2⁽¹⁺⁾=[((CH₃)3C)3C₆H₂PCH₂P((C₂H₅)2N)2]GaCl₄ 
• 819071-23-3 Cl₃GaP(2,4,6-tri-tert-butylphenyl)(CH₂) 
• 103194-55-4 2,4,6-tri-t-butylphenylmethylenephosphine(bis(tetracarbonyl)iron⁽⁰⁾) 
• 103194-56-5 (CO)4Fe((CH₃)3C)3C₆H₂PCH₂ 
• 103139-71-5 (CO)4Fe((CH₃)3C)3C₆H₂PCH₂ 

Relevant articles and documents

The phenylthio group as a new substituent on the 2-position of sterically protected 1-phosphaethenes

The phenylthio group was introduced to the sterically protected phosphaethene-system and 1-(phenylthio)-2-(2,4,6-trit-butylphenyl)-2-phosphaethenyllithium was generated. It has been shown that the lithium reagent behaves like a haloderivative, in terms of elimination, metalation, and coupling reaction, while the E/Z isomerization was observed for the phenylthio-derivative, and a 1,4-diphospha-1,3-butadiene as an oxidative coupling product was analyzed by X-ray.

Phosphinidene transfer reactions of the terminal phosphinidene complex Cp2Zr(PC6H2-2,4,6-t-Bu3)(PMe 3)

The terminal zirconium phosphinidene complex Cp2Zr(PR*)(PMe3) (R* = C6H2-2,4,6-t-Bu3) 2 has been synthesized in high yield, and its reactivity has been investigated. The compound Cp2ZrMe(PH

Phosphaalkene aus Monochlorphosphanen und Alkylidentriphenylphosphoranen

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