14917-59-0

Basic information

• Product Name: Benzoyl azide, 4-bromo-
• Synonyms: Benzoylazide, p-bromo- (6CI,8CI); 4-Bromobenzoyl azide; p-Bromobenzoyl azide
• CAS NO: 14917-59-0
• Molecular Formula: C₇H₄BrN₃O
• Molecular Weight: 229.04
• Mol File: 14917-59-0.mol
• Article Data: 19

Chemical Properties

• CAS DataBase Reference: Benzoyl azide, 4-bromo-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoyl azide, 4-bromo-(14917-59-0)
• EPA Substance Registry System: Benzoyl azide, 4-bromo-(14917-59-0)

Safety Data

• Hazard Codes: 3:
• Safety Statements: − and NOx. See also AZIDES." target="_blank">Explodes when heated above its melting point. When heated to decomposition it
• Hazardous Substances Data: 14917-59-0(Hazardous Substances Data)

Upstream product

• 5933-32-4 4-bromobenzoic acid hydrazide 
• 13195-79-4 2,2-dibromo-1-(4-bromophenyl)ethan-1-one 
• 1122-91-4 4-bromo-benzaldehyde 
• 37975-18-1 1-(4-bromophenyl)-3-(4-methoxyphenyl)propane-1,3-dione 
• 33170-68-2 1,3-bis-(4-bromo-phenyl)-propane-1,3-dione 
• 50-00-0 formaldehyd 
• 589-87-7 1,4-bromoiodobenzene 
• 201230-82-2 carbon monoxide 
• 586-76-5 4-Bromobenzoic acid 
• 586-75-4 4-chlorobenzoyl chloride 

Downstream Products

• 32767-01-4 N-acetyl-N'-(4-bromo-phenyl)-urea 
• 25203-36-5 methyl N-(4-bromophenyl)carbamate 
• 25203-35-4 1-propyl (4-bromophenyl)carbamate 
• 6269-49-4 2-isopropyl-5-methylphenyl (4-bromophenyl)carbamate 
• 57228-71-4 3-(4-bromo-phenylcarbamoyloxy)-cholest-5-ene 
• 100622-46-6 N-((4-bromophenyl)carbamoyl)benzamide 
• 13142-04-6 1-(4-bromophenyl)-3-(4-methylphenyl)urea 
• 13142-10-4 1-(4-bromophenyl)-3-(4-chlorophenyl)urea 

Relevant articles and documents

Hypervalent iodine in synthesis. Part 54: One-step conversion of aryl aldehydes to aroyl azides using a combined reagent of (diacetoxyiodo)benzene with sodium azide

Aroyl azides are readily prepared from the corresponding aryl aldehydes with the aid of (diacetoxyiodo)benzene (DIB) and sodium azide in high yields. (C) 2000 Elsevier Science Ltd.

Synthesis of Acyl Azides from 1,3-Diketones via Oxidative Cleavage of Two C-C Bonds

A metal-free PhI(OAc)2-mediated method for the synthesis of acyl azides through oxidative cleavage of 1,3-diketones is described. This method is shown to have a broad substrate scope, providing a useful tool for multiproduct synthesis in a single procedure. A possible reaction pathway is proposed based on mechanistic studies.

Copper-catalyzed N[sbnd]H/S[sbnd]H functionalization: A strategy for the synthesis of benzothiadiazine derivatives

A copper-mediated N[sbnd]S bond-forming reaction via N[sbnd]H/S[sbnd]H activation is described. This reaction occurs under mild conditions with high efficiency, step economy, and tolerates a wide variety of functional groups, providing an efficient means of accessing biologically important 1,2,4-benzothiadiazin-3(4H)-ones.