149179-59-9

Basic information

• Product Name: 4,5-Dihydro-4,4-dimethyl-5-morpholino-1-(2-nitrophenyl)-1,2,3-triazole
• Synonyms: 4,5-Dihydro-4,4-dimethyl-5-morpholino-1-(2-nitrophenyl)-1,2,3-triazole
• CAS NO: 149179-59-9
• Molecular Weight: 305.337
• Mol File: 149179-59-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4,5-Dihydro-4,4-dimethyl-5-morpholino-1-(2-nitrophenyl)-1,2,3-triazole(CAS DataBase Reference)
• NIST Chemistry Reference: 4,5-Dihydro-4,4-dimethyl-5-morpholino-1-(2-nitrophenyl)-1,2,3-triazole(149179-59-9)
• EPA Substance Registry System: 4,5-Dihydro-4,4-dimethyl-5-morpholino-1-(2-nitrophenyl)-1,2,3-triazole(149179-59-9)

Safety Data

• Hazardous Substances Data: 149179-59-9(Hazardous Substances Data)

Upstream product

• 110-91-8 morpholine 
• 1516-58-1 o-azidonitrobenzene 
• 78-84-2 isobutyraldehyde 

Downstream Products

• 149179-64-6 1-(2-Aminophenyl)-4,5-dihydro-4,4-dimethyl-5-morpholino-1,2,3-triazole 

Relevant articles and documents

v-Triazolines. Part 34. Thermal Behavior of 1-(2-Aminophenyl)-4,5-dihydro-5-morpholino-1,2,3-triazoles: New Synthesis of 2-Alkylquinoxalines

4,5-Dihydro-5-morpholino-1-(2-nitrophenyl)-1,2,3-triazoles 4 are prepared by reaction of an aldehyde with morpholine and the appropriate aryl azide.On reduction 1-(2-aminophenyl)-4,5-dihydro-5-morpholino-1,2,3-triazoles 5 are formed.Thermal rearrangement of compounds 5 affords unstable 2-alkyl-3-amino-1,2,3,4-tetrahydroquinoxalines 7, which undergo deamination to 2-alkyl-1,2-dihydroquinoxalines 8.Oxidation of these affords 2-alkylquinoxalines 10.The mechanism of thermal the rearrangement of triazoles 5 is investigated and discussed.