149206-46-2Relevant articles and documents
A novel synthesis of oxazolidin-5-one under basic condition
Karmakar,Mohapatra
, p. 1326 - 1328 (2001)
A simple and practical synthesis of oxazolidin-5-one is described under basic condition.
Process for Synthesizing Atazanavir
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Page/Page column 17, (2009/10/31)
This invention relates to a process for synthesizing Atazanvir, including novel intermediates and novel steps to various intermediates along the synthetic pathway.
Stanna-Brook rearrangement of carboxylic acid derivatives. Synthetic utility and mechanistic studies
Paleo, M. Rita,Calaza, M. Isabel,Grana, Paula,Sardina, F. Javier
, p. 1061 - 1063 (2007/10/03)
(Equation presented) The reaction of R3SnLi with carboxylic acid derivatives proceeds through a novel, very fast stanna-Brook rearrangement that generates α-alkoxyorganolithium compounds as intermediates. The outcome of these reactions depends on the nature of the carboxyl derivatives. Reaction of R3SnLi with ester derivatives gives rise to coupled products through a novel C-C bond formation reaction. Experimental evidence of the detailed reaction mechanism is provided.