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Dicyanoaurate, also known as dicyanoaurate (I) or sodium dicyanoaurate, is a chemical compound with the formula [Au(CN)2]-. It is a salt of a tetravalent gold anion and is commonly found in the form of its sodium salt, Na[Au(CN)2]. Dicyanoaurate is a strong oxidizing agent and is known for its versatile applications across different industries.

14950-87-9

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14950-87-9 Usage

Uses

Used in Gold Plating and Metal Finishing Industry:
Dicyanoaurate is used as a gold plating agent for enhancing the appearance and durability of various metal surfaces. Its strong oxidizing properties enable the deposition of a thin layer of gold, providing a shiny and corrosion-resistant finish.
Used in Mining Industry:
In the mining industry, dicyanoaurate is used for the extraction of gold from ore. Its oxidizing nature aids in the leaching process, allowing for the efficient recovery of gold from its ores.
Used in Analytical Chemistry:
Dicyanoaurate is employed as a reagent in analytical chemistry for the detection and quantification of various metals. Its unique chemical properties enable selective reactions with specific metal ions, facilitating accurate analysis and measurement.
Overall, dicyanoaurate is a versatile chemical with applications in various industries, including gold plating, metal finishing, mining, and analytical chemistry. Its strong oxidizing properties and ability to form stable complexes with metal ions make it a valuable compound for a wide range of applications.

Check Digit Verification of cas no

The CAS Registry Mumber 14950-87-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,9,5 and 0 respectively; the second part has 2 digits, 8 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 14950-87:
(7*1)+(6*4)+(5*9)+(4*5)+(3*0)+(2*8)+(1*7)=119
119 % 10 = 9
So 14950-87-9 is a valid CAS Registry Number.
InChI:InChI=1/2CN.Au/c2*1-2;/q;;-1/rC2AuN2/c4-1-3-2-5/q-1

14950-87-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name dicyanoaurate(1-)

1.2 Other means of identification

Product number -
Other names Aurate(1-), bis(cyano-kC)-

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:14950-87-9 SDS

14950-87-9Upstream product

14950-87-9Downstream Products

14950-87-9Related news

Adsorption of dicyanoaurate (cas 14950-87-9) (I) ions on highly oriented pyrolytic graphite07/19/2019

The adsorption of dicyanoaurate (I) onto the surface of activated carbon is the basis of modern techniques for gold extraction. The process is very efficient and has been the major factor in improving the productivity of the gold mining industry over the last 20 years. This paper describes a stu...detailed

Effect of thallium ions on the adsorption of cyanide-containing species from cyanide and dicyanoaurate (cas 14950-87-9) solutions on a polycrystalline gold electrode07/18/2019

The effect of thallium(I) ions on the adsorption of CN-containing species on a gold electrode from alkaline cyanide and dicyanoaurate solutions was studied by a radioactive labelling method. In cyanide solutions, adsorption of CN-containing species decreases linearly with the coverage of thalliu...detailed

Adsorption of cyanide-containing species from dicyanoaurate (cas 14950-87-9) solutions on gold electrodeposits07/17/2019

Adsorption of cyanide-containing species from 5 × 10−6–5 × 10−3 M KAu(CN)2 solutions in alkaline supporting electrolyte (0.1 M K3PO4) on gold electrodeposits was investigated over a wide potential range (from −1.5 to 1.5 V/SHE) using the radioactive labeling (14C) method. The results obtained...detailed

14950-87-9Relevant academic research and scientific papers

A 13C and 15N Solid-State NMR Study of Structural Disorder and Aurophilic Bonding in AuI and AuIII Cyanide Complexes

Harris, Kristopher J.,Wasylishen, Roderick E.

, p. 2316 - 2332 (2009)

Solid-state nuclear magnetic resonance has been used to study several cyanoaurates. Carbon-13 and nitrogen-15 NMR spectra of samples enriched with isotopically labeled 13C, 15N cyanide ligands were recorded for stationary samples and

Structure and multinuclear solid-state NMR of a highly birefringent lead-gold cyanide coordination polymer

Katz, Michael J.,Aguiar, Pedro M.,Batchelor, Raymond J.,Bokov, Alexei A.,Ye, Zuo-Guang,Kroeker, Scott,Leznoff, Daniel B.

, p. 3669 - 3676 (2006)

The coordination polymer Pb(H20)[Au(CN)2]a (1) was synthesized by the reaction of KAu(CN)2 and Pb(NO3) 2. The structure contains 1-D chains of lead(II)-OH2 linked via Au(CN)2- moieties, generating a 2-D slab; weak aurophilic interactions of 3.506(2) and 3.4885(5) A occur within and between slabs. The geometry about each lead(II) is bicapped trigonal prismatic, having six N-bound cyanides at the prism vertices and waters at two of the faces. Dehydration at 175 °C yields microcrystalline Pb[Au(CN) 2]2 (2), which, along with 1, was examined by 13C, 15N, 1H, and 207Pb solid-state NMR methods. TwO 15N resonances are assigned to the μ2-bridging and hydrogen-bonding cyanides in 1. Upon dehydration, the 207Pb NMR spectrum becomes axially symmetric and yields a reduced shielding span, indicating higher site symmetry, while the 13C and 15N spectra reveal a single cyanide. Although no single-crystal X-ray structure of 2 could be obtained, a structure is proposed on the basis of the NMR and X-ray powder data, consisting of a lead(II) center in a distorted square-prismatic environment, with cyanides present at each corner. The birefringence of single crystals of 1 is found to be 7.0 × 10-2 at room temperature. This value is large compared to that of most optical materials and can be attributed to the anisotropy of the 2-D slabs of 1, with all C≡N bonds aligned in the same direction by the polarizable lead(II) center.

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