1496541-79-7Relevant academic research and scientific papers
Organocatalytic reactions of α-trifluoromethylated esters with terminal alkenes at room temperature
Wang, Qi,Huan, Feng,Shen, Haiming,Xiao, Ji-Chang,Gao, Min,Yang, Xianjin,Murahashi, Shun-Ichi,Chen, Qing-Yun,Guo, Yong
, p. 12525 - 12531 (2014/01/17)
CF3-containing esters smoothly reacted with electron-deficient alkenes in the presence of a phosphine (2-dicyclohexylphosphino-2′, 4′,6′-triisopropylbiphenyl) organocatalyst at room temperature in an aerobic atmosphere. These Michael reactions efficiently provided products with a CF3 quaternary carbon center.
