149693-25-4Relevant academic research and scientific papers
Synthesis and Characterization of Thiolato- and Selenatoplatinum(II) Complexes with Bis(diphenylphosphino)alkanes
Jain, Vimal K.,Kannan, Shanmugapenumal,Butcher, Ray J.,Jasinski, J. P.
, p. 1509 - 1514 (1993)
The complexes i, SPh, C6H4Me-p or SePh; L-L = Ph2P(CH2)nPPh2 (n = 1-3)> have been prepared and their ability to act as bidentate ligands towards other metal species demonstrated.Proton, 31P and 195Pt NMR spectroscopy have been employed to ascertain their structures.A single-crystal X-ray structure determination of has established the mononuclear nature of the complex.The platinum atom is in a distorted square-planar environment with the selenium atoms and the chelating diphosphine ligand in a cis configuration.The four-membered PtPCP metallacyclic ring is non-planar.
