Synthesis and Characterization of Thiolato- and Selenatoplatinum(II) Complexes with Bis(diphenylphosphino)alkanes

DOI: 10.1039/DT9930001509

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1509 - 1514 (1993)

Update date:2022-08-03

Topics:

Authors:

Jain, Vimal K.

Kannan, Shanmugapenumal

Butcher, Ray J.

Jasinski, J. P.

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Article abstract of DOI:10.1039/DT9930001509

The complexes i, SPh, C6H4Me-p or SePh; L-L = Ph2P(CH2)nPPh2 (n = 1-3)> have been prepared and their ability to act as bidentate ligands towards other metal species demonstrated.Proton, 31P and 195Pt NMR spectroscopy have been employed to ascertain their structures.A single-crystal X-ray structure determination of has established the mononuclear nature of the complex.The platinum atom is in a distorted square-planar environment with the selenium atoms and the chelating diphosphine ligand in a cis configuration.The four-membered PtPCP metallacyclic ring is non-planar.

Full text of DOI:10.1039/DT9930001509

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